zldmЗаводская лаборатория. Диагностика материаловIndustrial laboratory. Diagnostics of materials1028-68612588-0187ООО «Издательство «ТЕСТ-ЗЛ»10.26896/1028-6861-2020-86-8-32-37zldm-1258Research ArticleИССЛЕДОВАНИЕ СТРУКТУРЫ И СВОЙСТВ. ФИЗИЧЕСКИЕ МЕТОДЫ ИССЛЕДОВАНИЯ И КОНТРОЛЯTESTING OF STRUCTURE AND PARAMETERS. PHYSICAL METHODS OF TESTING AND QUALITY CONTROLКонтроль поглощения водорода никелевыми пленками, полученными при вакуумно-магнетронном напылении циркониевого сплава, методом термоЭДСControl of hydrogen absorption by nickel films obtained upon magnetic spraying of zirconium alloy using the thermoEMF methodЛарионовВ. В.LarionovV. V.

Виталий Васильевич Ларионов

634050, г. Томск, пр. Ленина 30

Vitaliy V. Larionov

30, prosp. Lenina, Tomsk, 634050

lvv@tpu.ruШупэнСюйShupengXu

Сюй Шупэн

Xu Shupeng

КудияровВ. Н.KudiyarovV. N.

Виктор Николаевич Кудияров

Victor N. Kudiyarov

Национальный исследовательский томский политехнический университетРоссияNational Research Tomsk Polytechnic UniversityRussian Federation2020140820208683237Copyright © Ларионов В.В., Шупэн С., Кудияров В.Н., 20202020Ларионов В.В., Шупэн С., Кудияров В.Н.Larionov V.V., Shupeng X., Kudiyarov V.N.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.zldm.ru/jour/article/view/1258

Для защиты материалов из циркониевых сплавов от водорода часто используют никелевые пленки, формируемые на поверхности изделий. Адсорбция водорода проходит быстрее на никеле, поскольку последний активно с ним взаимодействует. Адсорбируя водород, никель окисляется и образует защитную пленку. Цель данной работы — разработка метода контроля поглощения водорода никелевыми пленками при вакуумно-магнетронном напылении и наводороживании с помощью определения термоЭДС. Циркониевый сплав Э110 насыщали водородом при температуре 350 °C и давлении 2 атм. из газовой фазы. Нанесение покрытия осуществляли на специализированной установке «Радуга спектр». Показано, что наличие никелевой пленки существенным образом влияет на проникновение водорода в сплав. Покрытие толщиной более 2 мкм, нанесенное магнетронным напылением на поверхность циркониевого сплава с 1 % Nb, защищает сплав от проникновения водорода практически полностью. При этом величина термоЭДС зависит от концентрации водорода в материале и толщины пленки. Приведены анализ ширины гистерезиса температурной петли термоЭДС и способ определения эффективной энергии активации проводимости наводороженного материала с пленкой никеля. Полученные результаты могут быть использованы при оценке концентрации водорода в материале и, соответственно, при его коррозионной защите.

Nickel films formed on the surface of zirconium alloys are often used to protect materials against hydrogen penetration. Hydrogen adsorption on nickel is faster since the latter actively interacts with hydrogen, oxidizes and forms a protective film. The goal of the study is to develop a method providing control of hydrogen absorption by nickel films during vacuum-magnetron sputtering and hydrogenation via measuring thermoEMF. Zirconium alloy E110 was saturated from the gas phase with hydrogen at a temperature of 350°C and a pressure of 2 atm. A specialized Rainbow Spectrum unit was used for coating. It is shown that a nickel film present on the surface significantly affects the hydrogen penetration into the alloy. A coating with a thickness of more than 2 μm deposited by magnetron sputtering on the surface of a zirconium alloy with 1% Nb, almost completely protects the alloy against hydrogen penetration. The magnitude of thermoemf depends on the hydrogen concentration in the zirconium alloy and film thickness. An analysis of the hysteresis width of the thermoEMF temperature loop and a method for determining the effective activation energy of the conductivity of a hydrogenated material coated with a nickel film are presented. The results of the study can be used in assessing the hydrogen concentration and, hence, corrosion protection of the material.

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The authors declare that there are no conflicts of interest present.