zldmЗаводская лаборатория. Диагностика материаловIndustrial laboratory. Diagnostics of materials1028-68612588-0187ООО «Издательство «ТЕСТ-ЗЛ»10.26896/1028-6861-2021-87-11-11-18zldm-1516Research ArticleАНАЛИЗ ВЕЩЕСТВАSUBSTANCES ANALYSISВзаимосвязи между элементным составом винограда, почвы с места его произрастания и винаCorrelations between the elemental composition of grapes, soils of the viticultural area and wineТемердашевЗ. А.TemerdashevZ. A.

Зауаль Ахлоович Темердашев - факультет химии и высоких технологий.

350040, Краснодар, ул. Ставропольская, д. 149

Zaual A. Temerdashev - Faculty of Chemistry and High Technologies

149, Stavropol’skaya ul., Krasnodar, 350040

abakumovleks@gmail.comАбакумовА. Г.AbakumovA. G.

Алексей Геннадьевич Абакумов - факультет химии и высоких технологий.

350040, Краснодар, ул. Ставропольская, д. 149

Aleksey G. Abakumov - Faculty of Chemistry and High Technologies

149, Stavropol’skaya ul., Krasnodar, 350040

ХалафянА. А.KhalafyanA. A.

Алексан Альбертович Халафян - факультет химии и высоких технологий.

350040, Краснодар, ул. Ставропольская, д. 149

Alexan A. Khalafyan – Faculty of Chemistry and High Technologies

149, Stavropol’skaya ul., Krasnodar, 350040

АгееваН. М.AgeevaN. M.

Наталья Михайловна Агеева

350072, Краснодар, ул. 40-летия Победы, д. 39

Natalia M. Ageeva

39, 40-letiya Pobedy гд., Krasnodar, 350072

Кубанский государственный университетРоссияKuban State UniversityRussian FederationСеверо-Кавказский федеральный научный центр садоводства, виноградарства, виноделияРоссияNorth Caucasian Federal Research Center of Horticulture, Viticulture, Wine-makingRussian Federation20212111202187111118Copyright © Темердашев З.А., Абакумов А.Г., Халафян А.А., Агеева Н.М., 20212021Темердашев З.А., Абакумов А.Г., Халафян А.А., Агеева Н.М.Temerdashev Z.A., Abakumov A.G., Khalafyan A.A., Ageeva N.M.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.zldm.ru/jour/article/view/1516

Работа посвящена установлению элементного состава почвы, винограда и вина и выявлению взаимосвязей между содержаниями в них ряда элементов. Объектами исследования были ягоды винограда сортов Мускат, Каберне и Мерло, образцы вин, произведенные из них, и пробы почв, отобранные с полей, соответствующих местам произрастания винограда. Концентрации Li, Mg, Al, K, Ca, V, Mn, Fe, Ni, Co, Cu, Zn, Rb, Cd, Pb, Ba, Na, Ti и Sr в почвах, винограде и винах определяли методом атомно-эмиссионной спектрометрии с индуктивно-связанной плазмой. Установление взаимосвязей между содержаниями элементов в изучаемых объектах проводили методами статистического моделирования с использованием программного обеспечения пакета STATISTICA. Характер распределения металлов в системе почва – виноград изучали для трех различных форм извлечения элементов из почв: определяли их валовое содержание, содержание кислоторастворимых и подвижных форм. Степень усвоения подвижных форм металлов почв ягодами винограда оценивали по показателю «биологический коэффициент поглощения». Для ягод винограда Мерло выше оказался биологический коэффициент поглощения Rb, Ti, Mg, Zn, Cu, Na, Fe, Al и Sr; Муската — K, Pb и Ni; Каберне — V и Mn. Наименьший биологический коэффициент поглощения в случае всех изучаемых сортов винограда наблюдали для Co, Ba и Ca. Каждый сорт винограда формировал свой индивидуальный элементный образ за счет различного характера усвоения изучаемых металлов. Переход металлов из ягоды в вино для всех сортов сопровождался снижением концентраций Mg, Al, K, Ca, Mn, Ni, Cu, Zn, Rb, Ba, Ti и Sr и повышением содержания V, Fe, Co, Pb и Na. Дискриминантным анализом установили обладающие наибольшими идентификационными свойствами металлы с учетом формы их содержания в почве. Полученные результаты могут быть использованы при установлении маркеров, определяющих сортовую и региональную принадлежность вин.

Study of the elemental composition of the soil-grape-wine chain and correlation relationships between the chain links is presented. The objects of the study were grapes of the Muscat, Cabernet and Merlot varieties, wine samples produced from them and soils of the viticultural areas. Concentrations of Li, Mg, Al, K, Ca, V, Mn, Fe, Ni, Co, Cu, Zn, Rb, Cd, Pb, Ba, Na, Ti and Sr in soils, grapes and wines were determined by inductively coupled plasma atomic emission spectrometry (ICP-AES). Relationships between the elemental composition of the objects under study were assessed by statistical modelling using the STATISTICA software. The character of metal distribution in the soil-grape chain was studied for three forms of the element extraction from soils. We determined their gross content, the content of acid-soluble and mobile forms. The degree of absorption of mobile forms of metals by grapes was estimated using «biological absorption coefficient»., Values of the biological absorption coefficient (BAC) of different metals depend on the grape variety. High BAC values are observed for Rb, Ti, Mg, Zn, Cu, Na, Fe, Al, and Sr in Merlot grapes; K, Pbm and Ni in Muscat; and for V and Mn in Cabernet. The lowest BAC values were observed for Co, Ba, and Ca in all grape varieties under study. Each grape variety formed its own individual elemental image due to the different nature of absorption of the studied metals. The transfer of metals from grape to wine for all considered varieties was accompanied by a decrease in the concentrations of Mg, Al, K, Ca, Mn, Ni, Cu, Zn, Rb, Ba, Ti, and Sr and by an increase in the content of V, Fe, Co, Pb, and Na. Discriminant analysis revealed the metals with the highest identification properties, considering their form present in the soil. The results obtained can be used when setting markers determining the varietal and regional origin of wines.

почвавиноградвиноподвижная и кислоторастворимая форма металловэлементный образдискриминантный анализсортовая и региональная принадлежностьsoilgrapeswinemobile and acid-soluble form of metalselemental imagediscriminant analysisvariety and regional originРабота выполнена при финансовой поддержке Российского фонда фундаментальных исследований (проект № 20-33-90046) с использованием научного оборудования ЦКП «Эколого-аналитический центр» Кубанского госуниверситетаReferencesTariba B. Metals in Wine-Impact on Wine Quality and Health Outcomes / Biol. Trace Elem. Res. 2011. Vol. 144. N 1 – 3. P. 143 – 156. DOI: 10.1007/s12011-011-9052-7Tariba B. Metals in Wine-Impact on Wine Quality and Health Outcomes / Biol. Trace Elem. Res. 2011. Vol. 144. N 1 – 3. P. 143 – 156. DOI: 10.1007/s12011-011-9052-7Deng Z-H., Zhang A., Yang Z-W., et al. A Human Health Risk Assessment of Trace Elements Present in Chinese Wine / Molecules. 2019. Article 24:248. DOI: 10.3390/molecules24020248Deng Z-H., Zhang A., Yang Z-W., et al. A Human Health Risk Assessment of Trace Elements Present in Chinese Wine / Molecules. 2019. Article 24:248. DOI: 10.3390/molecules24020248Wu H., Lin G., Tian L., et al. Origin verification of French red wines using isotope and elemental analyses coupled with chemometrics / Food Chem. 2020. Article 127760. DOI: 10.1016/j.foodchem.2020.127760Wu H., Lin G., Tian L., et al. Origin verification of French red wines using isotope and elemental analyses coupled with chemometrics / Food Chem. 2020. Article 127760. DOI: 10.1016/j.foodchem.2020.127760Temerdashev Z. A., Khalafyan A. A., Kaunova A. A., et al. Using neural networks to identify the regional and varietal origin of Cabernet and Merlot dry red wines produced in Krasnodar region / Foods Raw Mater. 2019. Vol. 7. N 1. P. 124 – 130. DOI: 10.21603/2308-4057-2019-1-124-130Temerdashev Z. A., Khalafyan A. A., Kaunova A. A., et al. Using neural networks to identify the regional and varietal origin of Cabernet and Merlot dry red wines produced in Krasnodar region / Foods Raw Mater. 2019. Vol. 7. N 1. P. 124 – 130. DOI: 10.21603/2308-4057-2019-1-124-130Bronzi B., Brilli C., Beone M., et al. Geographical identification of Chianti red wine based on ICP-MS element composition / Food Chem. 2020. Article 126248. DOI: 10.1016/j.foodchem.2020.126248Bronzi B., Brilli C., Beone M., et al. Geographical identification of Chianti red wine based on ICP-MS element composition / Food Chem. 2020. Article 126248. DOI: 10.1016/j.foodchem.2020.126248Urvieta R., Buscema F., Bottini R., et al. Phenolic and sensory profiles discriminate geographical indications for Malbec wines from different regions of Mendoza, Argentina / Food Chem. 2018. Vol. 265. P. 120 – 127. DOI: 10.1016/j.foodchem.2018.05.083Urvieta R., Buscema F., Bottini R., et al. Phenolic and sensory profiles discriminate geographical indications for Malbec wines from different regions of Mendoza, Argentina / Food Chem. 2018. Vol. 265. P. 120 – 127. DOI: 10.1016/j.foodchem.2018.05.083Kumar K., Schweiggert R., Patz C-D. Introducing a novel procedure for peak alignment in onedimensional 1H-NMR spectroscopy: A prerequisite for chemometric analyses of wine samples / Anal. Methods. 2020. Vol. 12. P. 3626 – 3636. DOI: 10.1039/D0AY01011AKumar K., Schweiggert R., Patz C-D. Introducing a novel procedure for peak alignment in onedimensional 1H-NMR spectroscopy: A prerequisite for chemometric analyses of wine samples / Anal. Methods. 2020. Vol. 12. P. 3626 – 3636. DOI: 10.1039/D0AY01011ABlotevogel S., Schreck E., Audry, S., et al. Contribution of soil elemental contents and Cu and Sr isotope ratios to the understanding of pedogenetic processes and mechanisms involved in the soil-to-grape transfer (Soave vineyard, Italy) / Geoderma. 2019. Vol. 343. P. 72 – 85. DOI: 10.1016/j.geoderma.2019.02.015Blotevogel S., Schreck E., Audry, S., et al. Contribution of soil elemental contents and Cu and Sr isotope ratios to the understanding of pedogenetic processes and mechanisms involved in the soil-to-grape transfer (Soave vineyard, Italy) / Geoderma. 2019. Vol. 343. P. 72 – 85. DOI: 10.1016/j.geoderma.2019.02.015Blotevogel S., Schreck E., Laplanche C., et al. Soil chemistry and meteorological conditions influence the elemental profiles of West European wines / Food Chem. 2019. Vol. 298. Artile 125033. DOI: 10.1016/j.foodchem.2019.125033Blotevogel S., Schreck E., Laplanche C., et al. Soil chemistry and meteorological conditions influence the elemental profiles of West European wines / Food Chem. 2019. Vol. 298. Artile 125033. DOI: 10.1016/j.foodchem.2019.125033Abakumov A. G., Titarenko V. O., Khalafyan A. A., et al. Grapes cultivar assignments using the identified elements-markers of grape berry and its different constituent parts / Analit. Kontrol’. 2019. Vol. 23. N 1. P. 61 – 70 [in Russian]. DOI: 10.15826/analitika.2019.23.1.002Abakumov A. G., Titarenko V. O., Khalafyan A. A., et al. Grapes cultivar assignments using the identified elements-markers of grape berry and its different constituent parts / Analit. Kontrol’. 2019. Vol. 23. N 1. P. 61 – 70 [in Russian]. DOI: 10.15826/analitika.2019.23.1.002Catarino S., Madeira M., Monteiro, F., et al. Effect of Bentonite Characteristics on the Elemental Composition of Wine / J. Agric. Food Chem. 2008. Vol. 56. N 1. P. 158 – 165. DOI: 10.1021/jf0720180Catarino S., Madeira M., Monteiro, F., et al. Effect of Bentonite Characteristics on the Elemental Composition of Wine / J. Agric. Food Chem. 2008. Vol. 56. N 1. P. 158 – 165. DOI: 10.1021/jf0720180Mierczynska-Vasilev A., Wahono S. K., Smith, P. A., et al. Using Zeolites To Protein Stabilize White Wines / ACS Sustain. Chem. Eng. 2019. Vol. 7. N 14. P. 12240 – 12247. DOI: 10.1021/acssuschemeng.9b01583Mierczynska-Vasilev A., Wahono S. K., Smith, P. A., et al. Using Zeolites To Protein Stabilize White Wines / ACS Sustain. Chem. Eng. 2019. Vol. 7. N 14. P. 12240 – 12247. DOI: 10.1021/acssuschemeng.9b01583Ubeda C., Lambert-Royo M. I., Cortiella M., et al. Chemical, Physical, and Sensory Effects of the Use of Bentonite at Different Stages of the Production of Traditional Sparkling Wines / Foods. 2021. Article 10(2): 390. DOI: 10.3390/foods10020390Ubeda C., Lambert-Royo M. I., Cortiella M., et al. Chemical, Physical, and Sensory Effects of the Use of Bentonite at Different Stages of the Production of Traditional Sparkling Wines / Foods. 2021. Article 10(2): 390. DOI: 10.3390/foods10020390Zhao H., Tang J., Yang Q. Effects of geographical origin, variety, harvest season, and their interactions on multi-elements in cereal, tuber, and legume crops for authenticity / J. Food Compos. Anal. 2021. Vol. 100. Article 103900. DOI: 10.1016/j.jfca.2021.103900Zhao H., Tang J., Yang Q. Effects of geographical origin, variety, harvest season, and their interactions on multi-elements in cereal, tuber, and legume crops for authenticity / J. Food Compos. Anal. 2021. Vol. 100. Article 103900. DOI: 10.1016/j.jfca.2021.103900Foroni F., Vignando M., Aiello M., et al. The smell of terroir! Olfactory discrimination between wines of different grape variety and different terroir / Food Qual. Prefer. 2017. Vol. 58. P. 18 – 23. DOI: 10.1016/j.foodqual.2016.12.012Foroni F., Vignando M., Aiello M., et al. The smell of terroir! Olfactory discrimination between wines of different grape variety and different terroir / Food Qual. Prefer. 2017. Vol. 58. P. 18 – 23. DOI: 10.1016/j.foodqual.2016.12.012van Leeuwen C., Roby J. -P., de Rességuier L. Soil-related terroir factors: a review / OENO One. 2018. Vol. 52. N 2. P. 173 – 188. DOI: 10.20870/oeno-one.2018.52.2.2208van Leeuwen C., Roby J. -P., de Rességuier L. Soil-related terroir factors: a review / OENO One. 2018. Vol. 52. N 2. P. 173 – 188. DOI: 10.20870/oeno-one.2018.52.2.2208Maltman A. Minerality in wine: A geological perspective / J. Wine Res. 2013. Vol. 24. N 3. P. 169 – 181. DOI: 10.1080/09571264.2013.793176Maltman A. Minerality in wine: A geological perspective / J. Wine Res. 2013. Vol. 24. N 3. P. 169 – 181. DOI: 10.1080/09571264.2013.793176Marschner P. Marschner’s Mineral Nutrition of Higher Plants. 3rd Ed. — London, UK: Elsevier, 2012. — 643 p.Marschner P. Marschner’s Mineral Nutrition of Higher Plants. 3rd Ed. — London, UK: Elsevier, 2012. — 643 p.Kaunova A. A., Titarenko V. O., Temerdashev Z. A., et al. Analysis of some approaches for assessing the quality, authenticity and regional origin of wine / Zavod. Lab. Diagn. Mater. 2016. Vol. 82. N 8. P. 69 – 74 [in Russian]. DOI: 10.15826/analitika.2016.20.2.004Kaunova A. A., Titarenko V. O., Temerdashev Z. A., et al. Analysis of some approaches for assessing the quality, authenticity and regional origin of wine / Zavod. Lab. Diagn. Mater. 2016. Vol. 82. N 8. P. 69 – 74 [in Russian]. DOI: 10.15826/analitika.2016.20.2.004Zioła-Frankowska A., Frankowski M. Determination of metals and metalloids in wine using inductively coupled plasma optical emission spectrometry and mini-torch / Food Anal. Methods. 2017. Vol. 10. P. 180 – 190. DOI: 10.1007/s12161-016-0567-6Zioła-Frankowska A., Frankowski M. Determination of metals and metalloids in wine using inductively coupled plasma optical emission spectrometry and mini-torch / Food Anal. Methods. 2017. Vol. 10. P. 180 – 190. DOI: 10.1007/s12161-016-0567-6Bertin C., Yang X., Weston L. A. The role of root exudates and allelochemicals in the rhizo-sphere / Plant Soil. 2003. Vol. 256. P. 67 – 83. DOI: 10.1023/A:1026290508166Bertin C., Yang X., Weston L. A. The role of root exudates and allelochemicals in the rhizo-sphere / Plant Soil. 2003. Vol. 256. P. 67 – 83. DOI: 10.1023/A:1026290508166Rao C. R. M., Sahuquillo A., Lopez Sanchez J. F. A Review of the different methods applied in environmental geo-chemistry for single and sequential extraction of trace elements in soils and related materials / Water Air Soil Pollut. 2008. Vol. 189. P. 291 – 333. DOI: 10.1007/s11270-007–9564-0Rao C. R. M., Sahuquillo A., Lopez Sanchez J. F. A Review of the different methods applied in environmental geo-chemistry for single and sequential extraction of trace elements in soils and related materials / Water Air Soil Pollut. 2008. Vol. 189. P. 291 – 333. DOI: 10.1007/s11270-007–9564-0Hill T., Lewicki P. Statistics Methods and Applications. — Tulsa, OK: StatSoft, 2007. — 719 p.Hill T., Lewicki P. Statistics Methods and Applications. — Tulsa, OK: StatSoft, 2007. — 719 p.Zinicovscaia I., Sturza R., Gurmeza I., et al. Metal bioaccumulation in the soil-leaf-fruit system determined by neutron activation analysis / J. Food Meas. Charact. 2018. Vol. 13. N 1. P. 592 – 601. DOI: 10.1007/s11694-018-9972-4Zinicovscaia I., Sturza R., Gurmeza I., et al. Metal bioaccumulation in the soil-leaf-fruit system determined by neutron activation analysis / J. Food Meas. Charact. 2018. Vol. 13. N 1. P. 592 – 601. DOI: 10.1007/s11694-018-9972-4Amorós J. A., Pérez-de-los Reyes C., García Navarro F. J., et al. Bioaccumulation of mineral elements in grapevine varieties cultivated in «La Mancha» / J. Soil Sci. Plant Nutr. 2013. Vol. 176. N 6. P. 843 – 850. DOI: 10.1002/jpln.201300015Amorós J. A., Pérez-de-los Reyes C., García Navarro F. J., et al. Bioaccumulation of mineral elements in grapevine varieties cultivated in «La Mancha» / J. Soil Sci. Plant Nutr. 2013. Vol. 176. N 6. P. 843 – 850. DOI: 10.1002/jpln.201300015Redan B. W. Processing Aids in Food and Beverage Manufacturing: Potential Source of Elemental and Trace Metal Contaminants / J. Agric. Food Chem. 2020. Vol. 68. N 46. P. 13001 – 13007. DOI: 10.1021/acs.jafc.9b08066Redan B. W. Processing Aids in Food and Beverage Manufacturing: Potential Source of Elemental and Trace Metal Contaminants / J. Agric. Food Chem. 2020. Vol. 68. N 46. P. 13001 – 13007. DOI: 10.1021/acs.jafc.9b08066Nicolini G., Larcher R., Pangrazzi P., Bontempo L. Changes in the contents of micro- and trace-elements in wine due to winemaking treatments / Vitis — J. Grapevine Res. 2004. Vol. 43. N 1. P. 41 – 45. DOI: 10.5073/vitis.2004.43.41–45Nicolini G., Larcher R., Pangrazzi P., Bontempo L. Changes in the contents of micro- and trace-elements in wine due to winemaking treatments / Vitis — J. Grapevine Res. 2004. Vol. 43. N 1. P. 41 – 45. DOI: 10.5073/vitis.2004.43.41–45da Silva J., da Silva G., Parente D., et al. Biological diversity of carbon assimilation among isolates of the yeast Dekkera bruxellensis from wine and fuel-ethanol industrial processes / FEMS Yeast Res. 2019. Vol. 19. N 3. Article foz022. DOI: 10.1093/femsyr/foz022da Silva J., da Silva G., Parente D., et al. Biological diversity of carbon assimilation among isolates of the yeast Dekkera bruxellensis from wine and fuel-ethanol industrial processes / FEMS Yeast Res. 2019. Vol. 19. N 3. Article foz022. DOI: 10.1093/femsyr/foz022Ren M., Liu S., Li R., et al. Clarifying effect of different fining agents on mulberry wine / Int. J. Food Sci. Technol. 2020. Vol. 55. N 4. P. 1578 – 1585. DOI: 10.1111/ijfs.14433Ren M., Liu S., Li R., et al. Clarifying effect of different fining agents on mulberry wine / Int. J. Food Sci. Technol. 2020. Vol. 55. N 4. P. 1578 – 1585. DOI: 10.1111/ijfs.14433

The authors declare that there are no conflicts of interest present.