zldmЗаводская лаборатория. Диагностика материаловIndustrial laboratory. Diagnostics of materials1028-68612588-0187ООО «Издательство «ТЕСТ-ЗЛ»10.26896/1028-6861-2021-87-12-26-32zldm-1539Research ArticleИССЛЕДОВАНИЕ СТРУКТУРЫ И СВОЙСТВ. ФИЗИЧЕСКИЕ МЕТОДЫ ИССЛЕДОВАНИЯ И КОНТРОЛЯTESTING OF STRUCTURE AND PARAMETERS. PHYSICAL METHODS OF TESTING AND QUALITY CONTROLИсследование высокотемпературных металлокерамических фильтров на основе Ti – AlStudy of Ti – Al based high-temperature cermet filtersКирилловА. О.KirillovA. O.

Андрей Олегович Кириллов

142432, Московская обл., Черноголовка, ул. Академика Осипьяна, д. 8

Andrey O. Kirillov

8, ul. Akademika Osipyana, Chernogolovka, Moscow obl., 142432

kira@ism.ac.ruУваровВ. И.UvarovV. I.

Валерий Иванович Уваров

142432, Московская обл., Черноголовка, ул. Академика Осипьяна, д. 8

Valeriy I. Uvarov

8, ul. Akademika Osipyana, Chernogolovka, Moscow obl., 142432

КапустинР. Д.KapustinR. D.

Роман Дмитриевич Капустин

142432, Московская обл., Черноголовка, ул. Академика Осипьяна, д. 8

Roman D. Kapustin

8, ul. Akademika Osipyana, Chernogolovka, Moscow obl., 142432

Институт структурной макрокинетики и проблем материаловедения имени А. Г. Мержанова РАН (ИСМАН)РоссияA. G. Merzhanov Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences (ISMAN)Russian Federation20211812202187122329Copyright © Кириллов А.О., Уваров В.И., Капустин Р.Д., 20212021Кириллов А.О., Уваров В.И., Капустин Р.Д.Kirillov A.O., Uvarov V.I., Kapustin R.D.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.zldm.ru/jour/article/view/1539

Для работы в условиях воздействия агрессивных сред и/или высоких температур необходимы улучшенные эксплуатационные характеристики и долговечность фильтровального оборудования. Интерметаллидная система Ti – Al сочетает в себе низкую плотность с высокой прочностью, а также обладает стойкостью к окислению и коppозии при повышенных температурах. В работе представлены результаты исследования изделий (фильтров) с наноразмерными порами на основе высокотемпературной Ti – Al-металлокерамики. Фильтры из смеси порошков Ti и Al (массовое соотношение 40:60) получали с применением метода теплового взрыва. Методами РФА установлено, что синтезированный материал состоит из двух основных фаз: TiAl3 и Al2O3. Анализ микроструктуры показал наличие крупноразмерных структур TiAl3 и шарообразных агрегатов Al2O3, которые обволакиваются наноструктурированным TiAl3. Помимо этого, во всем объеме порового пространства материала наблюдаются наноразмерные волокнистые соединения TiAl3, образующие многоуровневую развитую паутинообразную структуру. Открытая пористость материала составила 48 %, величина пор – 0,1 – 0,2 мкм, эффективность пористого материала – 99,999 %, сопротивление газовому потоку – 100 мм водного столба, фильтрационный показатель – 0,062. Термические испытания выявили возможность эффективного применения фильтров в условиях высоких (до 800 °C) температур, в том числе при воздействии агрессивных сред, что обусловлено химически- и жаростойкой бинарной структурой материала. Полученные результаты могут быть использованы при совершенствовании методики разработки и эксплуатации высокотемпературных металлокерамических фильтров на основе Ti – Al.

Operation in corrosive media and/or at high temperatures requires improved characteristics of the performance and durability of filtering equipment. The Ti – Al intermetallic system combines low density with high strength and exhibits high resistance to oxidation and corrosion at elevated temperatures. We present the results of studying high-temperature Ti – Al cermet products (filters) with nanoscale pores. Filters were obtained from a mixture of Ti and Al powders (mass ratio 40:60) by thermal explosion. XRD methods showed that the synthesized material consists of two main phases: TiAl3 and Al2O3. The microstructure analysis revealed the presence of large-sized TiAl3 structures and spherical Al2O3 aggregates enveloped by nanostructured TiAl3. Moreover, nanoscale fibrous TiAl3 compounds forming a multilevel developed cobweb-like structure are observed in the entire volume of the pore space of the material. The open porosity of the material was 48%, the pore size was 0.1 – 0.2 μm, the efficiency of the porous material was 99.999%, the resistance to gas flow was 100 mm of water column, and the filtration index was 0.062. Thermal tests revealed the possibility of effective use of filters under conditions of elevated (up to 800°C) temperatures and corrosive media due to the chemically stable and heat-resistant binary structure of the material. The results obtained can be used to improve the methodology of the development and operation of high-temperature cermet filters based on Ti – Al.

металлокерамикафильтрыгорениесамораспространяющийся высокотемпературный синтезтепловой взрывнанопористая структураcermetsfilterscombustionself-propagating high-temperature synthesisthermal explosionnanoporous structureReferencesAli A., Tufa R., Macedonio F., et al. Membrane technology in renewable-energy-driven desalination / Renew. Sustainable Energy Rev. 2018. Vol. 81. N 1. P. 1 – 21. DOI: 10.1016/j.rser.2017.07.047Ali A., Tufa R., Macedonio F., et al. Membrane technology in renewable-energy-driven desalination / Renew. Sustainable Energy Rev. 2018. Vol. 81. N 1. P. 1 – 21. DOI: 10.1016/j.rser.2017.07.047Tang C., Yang Z., Guo H., el al. Potable Water Reuse through Advanced Membrane Technology / Environ. Sci. Technol. 2018. Vol. 52. N 18. P. 10215 – 10223. DOI: 10.1021/acs.est.8b00562Tang C., Yang Z., Guo H., el al. Potable Water Reuse through Advanced Membrane Technology / Environ. Sci. Technol. 2018. Vol. 52. N 18. P. 10215 – 10223. DOI: 10.1021/acs.est.8b00562Nunes S. P., Peinemann K.-V. Membrane Technology: in the Chemical Industry. 2nd edition. — Weinheim: Wiley-VCH, 2006. — 358 р.Nunes S. P., Peinemann K.-V. Membrane Technology: in the Chemical Industry. 2nd edition. — Weinheim: Wiley-VCH, 2006. — 358 р.Li C., Sun W., Lu Z., el al. Ceramic nanocomposite membranes and membrane fouling: а review / Water Res. 2020. Vol. 175. P. 115674. DOI: 10.1016/j.watres.2020.115674Li C., Sun W., Lu Z., el al. Ceramic nanocomposite membranes and membrane fouling: а review / Water Res. 2020. Vol. 175. P. 115674. DOI: 10.1016/j.watres.2020.115674Munirasu S., Haija M., Banat F. Use of membrane technology for oil field and refinery produced water treatment (а review) / Process Saf. Environ. Prot. 2016. Vol. 100. P. 183 – 202. DOI: 10.1016/j.psep.2016.01.010Munirasu S., Haija M., Banat F. Use of membrane technology for oil field and refinery produced water treatment (а review) / Process Saf. Environ. Prot. 2016. Vol. 100. P. 183 – 202. DOI: 10.1016/j.psep.2016.01.010Shi X., Tal G., Hankins N., et al. Fouling and cleaning of ultrafiltration membranes: a review / J. Water Proc. Engi. 2014. Vol. 1. P. 121 – 138. DOI: 10.1016/j.jwpe.2014.04.003Shi X., Tal G., Hankins N., et al. Fouling and cleaning of ultrafiltration membranes: a review / J. Water Proc. Engi. 2014. Vol. 1. P. 121 – 138. DOI: 10.1016/j.jwpe.2014.04.003Andrianov A. The study and optimization of the installations water purification by ultrafiltration: autoref. dis. — Moscow: MGSU, 2003. — 24 p. [in Russian].Andrianov A. The study and optimization of the installations water purification by ultrafiltration: autoref. dis. — Moscow: MGSU, 2003. — 24 p. [in Russian].Kamato Y., Suzuki Y. Reactive synthesis of porous MgAl2O4 membranes on a macroporous Al2O3-based ceramic tube toward cross-flow ultrafiltration / J. Ceram. Soc. 2019. Vol. 127. P. 267 – 271. DOI: 10.2109/jcersj2.18202Kamato Y., Suzuki Y. Reactive synthesis of porous MgAl2O4 membranes on a macroporous Al2O3-based ceramic tube toward cross-flow ultrafiltration / J. Ceram. Soc. 2019. Vol. 127. P. 267 – 271. DOI: 10.2109/jcersj2.18202Ulbricht M. Advanced functional polymer membranes / Pol. 2006. Vol. 47. N 7. P. 2217 – 2262. DOI: 10.1016/j.polymer.2006.01.084Ulbricht M. Advanced functional polymer membranes / Pol. 2006. Vol. 47. N 7. P. 2217 – 2262. DOI: 10.1016/j.polymer.2006.01.084Zearley T., Summers S. Removal of trace organic micropollutants by drinking water biological filters / Environ. Sci. Technol. 2012. Vol. 46. N 17. P. 9412 – 9419. DOI: 10.1021/es301428eZearley T., Summers S. Removal of trace organic micropollutants by drinking water biological filters / Environ. Sci. Technol. 2012. Vol. 46. N 17. P. 9412 – 9419. DOI: 10.1021/es301428eMuhammad N., Sinha R., Krishnan E., et al. Ceramic filter for small system drinking water treatment: evaluation of membrane pore size and importance of integrity monitoring / J. Environ. Eng. 2009. Vol. 135. N 11. P. 1181 – 1191. DOI: 10.1061/(ASCE)EE.1943-7870.0000084Muhammad N., Sinha R., Krishnan E., et al. Ceramic filter for small system drinking water treatment: evaluation of membrane pore size and importance of integrity monitoring / J. Environ. Eng. 2009. Vol. 135. N 11. P. 1181 – 1191. DOI: 10.1061/(ASCE)EE.1943-7870.0000084Zhu B., Duke M., Dumée L., et al. Short Review on Porous Metal Membranes — Fabrication, Commercial Products and Applications / Membranes. 2018. Vol. 8. N 3. P. 83. DOI: 10.3390/membranes8030083Zhu B., Duke M., Dumée L., et al. Short Review on Porous Metal Membranes — Fabrication, Commercial Products and Applications / Membranes. 2018. Vol. 8. N 3. P. 83. DOI: 10.3390/membranes8030083Zang C., Tang H., Wang J. Research progress on mechanical properties of sintered metallic porous materials / Rare Met. Mater. Eng. 2009. Vol. 38. P. 437 – 442.Zang C., Tang H., Wang J. Research progress on mechanical properties of sintered metallic porous materials / Rare Met. Mater. Eng. 2009. Vol. 38. P. 437 – 442.Yao J., Yang G., Li C. Fabrication of Porous Stainless Steel by Flame Spraying of Semimolten Particles / Mater. Manuf. Process. 2014. Vol. 29. N 10. P. 1253 – 1259. DOI: 10.1080/10426914.2014.9414792014Yao J., Yang G., Li C. Fabrication of Porous Stainless Steel by Flame Spraying of Semimolten Particles / Mater. Manuf. Process. 2014. Vol. 29. N 10. P. 1253 – 1259. DOI: 10.1080/10426914.2014.9414792014Kim Y. M., Kim S. J., Kim Y. S. Overview of systems engineering approaches for a large-scale seawater desalination plant with a reverse osmosis network / Desalination. 2009. Vol. 238. N 1 – 3. P. 312 – 332. DOI: 10.1016/j.desal.2008.10.004Kim Y. M., Kim S. J., Kim Y. S. Overview of systems engineering approaches for a large-scale seawater desalination plant with a reverse osmosis network / Desalination. 2009. Vol. 238. N 1 – 3. P. 312 – 332. DOI: 10.1016/j.desal.2008.10.004Shen P., Gao H., Song M. Preparation and Pore Structure Stability at High Temperature of Porous Fe – Al Intermetallics / J. Mater. Eng. Perf. 2013. Vol. 22. P. 3959 – 3966. DOI: 10.1007/s11665-013-0703-zShen P., Gao H., Song M. Preparation and Pore Structure Stability at High Temperature of Porous Fe – Al Intermetallics / J. Mater. Eng. Perf. 2013. Vol. 22. P. 3959 – 3966. DOI: 10.1007/s11665-013-0703-zHammel E., Ighodaro O., Okoli O. Processing and properties of advanced porous ceramics: An application based review / Ceram. Int. 2014. Vol. 40. N 10A. P. 15351 – 15370. DOI: 10.1016/j.ceramint.2014.06.095Hammel E., Ighodaro O., Okoli O. Processing and properties of advanced porous ceramics: An application based review / Ceram. Int. 2014. Vol. 40. N 10A. P. 15351 – 15370. DOI: 10.1016/j.ceramint.2014.06.095Deng X., Wang J., Liu J., et al. Preparation and characterization of porous mullite ceramics via foam-gelcasting / Ceram. Int. 2015. Vol. 41. P. 9009 – 9017. DOI: 10.1016/j.ceramint.2015.03.237.Deng X., Wang J., Liu J., et al. Preparation and characterization of porous mullite ceramics via foam-gelcasting / Ceram. Int. 2015. Vol. 41. P. 9009 – 9017. DOI: 10.1016/j.ceramint.2015.03.237.Nguyen-Manh D., Cawkwell M., Gröger R., et al. Dislocations in materials with mixed covalent and metallic bonding / Mater. Sci. Eng. A. 2005. Vol. 400 – 401. P. 68 – 71. DOI: 10.1016/j.msea.2005.03.081Nguyen-Manh D., Cawkwell M., Gröger R., et al. Dislocations in materials with mixed covalent and metallic bonding / Mater. Sci. Eng. A. 2005. Vol. 400 – 401. P. 68 – 71. DOI: 10.1016/j.msea.2005.03.081Wang Z., Jiao X., Feng P., et al. Highly porous open cellular TiAl-based intermetallics fabricated by thermal explosion with space holder process / Intermetallics. 2016. Vol. 68. P. 95 – 100. DOI: 10.1016/j.intermet.2015.09.010Wang Z., Jiao X., Feng P., et al. Highly porous open cellular TiAl-based intermetallics fabricated by thermal explosion with space holder process / Intermetallics. 2016. Vol. 68. P. 95 – 100. DOI: 10.1016/j.intermet.2015.09.010Dong H., Jiang Y., He Y., Song M. Formation of porous Ni – Al intermetallics through pressureless reaction synthesis / J. Alloy Compd. 2009. Vol. 484. P. 907 – 913. DOI: 10.1016/j.jallcom.2009.05.079Dong H., Jiang Y., He Y., Song M. Formation of porous Ni – Al intermetallics through pressureless reaction synthesis / J. Alloy Compd. 2009. Vol. 484. P. 907 – 913. DOI: 10.1016/j.jallcom.2009.05.079Ran H., Niu J., Song B., et al. Microstructure and properties of Ti5Si3-based porous intermetallic compounds fabricated via combustion synthesis / J. Alloy Compd. 2014. Vol. 612. P. 337 – 342. DOI: 10.1016/j.jallcom.2014.05.216Ran H., Niu J., Song B., et al. Microstructure and properties of Ti5Si3-based porous intermetallic compounds fabricated via combustion synthesis / J. Alloy Compd. 2014. Vol. 612. P. 337 – 342. DOI: 10.1016/j.jallcom.2014.05.216Boyarchenko O., Kamynina O., Sytschev A., et al. Synthesis of Ti – Al-based materials by thermal explosion / Int. J. Self-Propag. High-Temp. Synth. 2010. Vol. 19. P. 285 – 291. DOI: 10.3103/S1061386210040084Boyarchenko O., Kamynina O., Sytschev A., et al. Synthesis of Ti – Al-based materials by thermal explosion / Int. J. Self-Propag. High-Temp. Synth. 2010. Vol. 19. P. 285 – 291. DOI: 10.3103/S1061386210040084Kamynina O., Bozhko S., Boyarchenko O., et al. Formation of the Structure and Phase Composition of Ti – Al – Ta-Based Materials / Russ. J. Non-ferrous Metals. 2016. Vol. 57. N 5. P. 489 – 496. DOI: 10.3103/S1067821216050072Kamynina O., Bozhko S., Boyarchenko O., et al. Formation of the Structure and Phase Composition of Ti – Al – Ta-Based Materials / Russ. J. Non-ferrous Metals. 2016. Vol. 57. N 5. P. 489 – 496. DOI: 10.3103/S1067821216050072Li X., Cheng G., Xue W., et al. Wear and corrosion resistant coatings formed by microarc oxidation on TiAl alloy / Mater. Chem. Phys. 2008. Vol. 107. P. 148 – 152. DOI: 10.1016/j.matchemphys.2007.06.067Li X., Cheng G., Xue W., et al. Wear and corrosion resistant coatings formed by microarc oxidation on TiAl alloy / Mater. Chem. Phys. 2008. Vol. 107. P. 148 – 152. DOI: 10.1016/j.matchemphys.2007.06.067Zollinger J., Lapin J., Daloz D., Combeau H. Influence of oxygen on solidification behaviour of cast TiAl-based alloys / Intermetallics. 2007. Vol. 15. P. 1343 – 1350. DOI: 10.1016/j.intermet.2007.04.002Zollinger J., Lapin J., Daloz D., Combeau H. Influence of oxygen on solidification behaviour of cast TiAl-based alloys / Intermetallics. 2007. Vol. 15. P. 1343 – 1350. DOI: 10.1016/j.intermet.2007.04.002Lapin J. Creep behaviour of a cast TiAl-based alloy for industrial applications / Intermetallics. 2016. Vol. 14. N 2. P. 115 – 122. DOI: 10.1016/j.intermet.2005.03.008.Lapin J. Creep behaviour of a cast TiAl-based alloy for industrial applications / Intermetallics. 2016. Vol. 14. N 2. P. 115 – 122. DOI: 10.1016/j.intermet.2005.03.008.Kiparisov S. S., Libenson G. A. Powder metallurgy. — Moscow: Metallurgiya, 1980. — 496 p. [in Russian].Kiparisov S. S., Libenson G. A. Powder metallurgy. — Moscow: Metallurgiya, 1980. — 496 p. [in Russian].Alymov M., Shustov V., Uvarov V. Gradient-structure titanium carbide filter for liquid and gas filtration / Inorg Mater. 2015. Vol. 51. P. 984 – 990. DOI: 10.1134/S0020168515090010Alymov M., Shustov V., Uvarov V. Gradient-structure titanium carbide filter for liquid and gas filtration / Inorg Mater. 2015. Vol. 51. P. 984 – 990. DOI: 10.1134/S0020168515090010Aani S., Mustafa T., Hilal N. Ultrafiltration membranes for wastewater and water process engineering: A comprehensive statistical review over the past decade / J. Water Proc. Eng. 2020. Vol. 35. P. 101241. DOI: 10.1016/j.jwpe.2020.101241Aani S., Mustafa T., Hilal N. Ultrafiltration membranes for wastewater and water process engineering: A comprehensive statistical review over the past decade / J. Water Proc. Eng. 2020. Vol. 35. P. 101241. DOI: 10.1016/j.jwpe.2020.101241Borovinskaya I., Merzhanov A., Uvarov V. Capillary-porous SHS materials for filtration of liquids and gases / Science-production. 2001. N 10. P. 28 – 32.Borovinskaya I., Merzhanov A., Uvarov V. Capillary-porous SHS materials for filtration of liquids and gases / Science-production. 2001. N 10. P. 28 – 32.Shiryaev A. Thermodynamics of SHS: Modern approach / Int. J. Self-Propag. High-Temp Synth. 1995. N 4. P. 351 – 362.Shiryaev A. Thermodynamics of SHS: Modern approach / Int. J. Self-Propag. High-Temp Synth. 1995. N 4. P. 351 – 362.Moore J., Feng H. Combustion synthesis of advanced materials. Part I. Reaction parameters / Progress Mater. Sci. 1995. Vol. 39. P. 243 – 273.Moore J., Feng H. Combustion synthesis of advanced materials. Part I. Reaction parameters / Progress Mater. Sci. 1995. Vol. 39. P. 243 – 273.Shen P., He Y., Gao H. Development of a new graded-porosity FeAl alloy by elemental reactive synthesis / Desalination. 2009. Vol. 249. P. 29 – 33. DOI: 10.1016/j.desal.2009.06.012Shen P., He Y., Gao H. Development of a new graded-porosity FeAl alloy by elemental reactive synthesis / Desalination. 2009. Vol. 249. P. 29 – 33. DOI: 10.1016/j.desal.2009.06.012Arakawa Y., Kobashi M., Kanetake N. Foaming behavior of long-scale Al – Ti intermetallic foam by SHS mode combustion reaction / Intermetallics. 2013. Vol. 41. P. 22 – 27. DOI: 10.1016/j.intermet.2013.04.004Arakawa Y., Kobashi M., Kanetake N. Foaming behavior of long-scale Al – Ti intermetallic foam by SHS mode combustion reaction / Intermetallics. 2013. Vol. 41. P. 22 – 27. DOI: 10.1016/j.intermet.2013.04.004Sohn H., Wang X. Self-Propagating High Temperature Synthesis (SHS) of Intermetallic Compounds Titanium and Nickel Aluminides / Mater Manuf. Processes. 1994. Vol. 9. N 1. P. 75 – 87. DOI: 10.1080/10426919408934886Sohn H., Wang X. Self-Propagating High Temperature Synthesis (SHS) of Intermetallic Compounds Titanium and Nickel Aluminides / Mater Manuf. Processes. 1994. Vol. 9. N 1. P. 75 – 87. DOI: 10.1080/10426919408934886Shi Q., Qin B., Feng P., Ran H. Synthesis, microstructure and properties of Ti – Al porous intermetallic compounds prepared by a thermal explosion reaction / RSC Advances. 2015. Vol. 5. P. 46339 – 46347. DOI: 10.1039/C5RA04047GShi Q., Qin B., Feng P., Ran H. Synthesis, microstructure and properties of Ti – Al porous intermetallic compounds prepared by a thermal explosion reaction / RSC Advances. 2015. Vol. 5. P. 46339 – 46347. DOI: 10.1039/C5RA04047GBakunov V. S., Balkevich V. L., Guzman I. Ya., Lukin E. S. Workshop on the technology of ceramics and refractories. — Moscow: Stroyizdat, 1972. — 352 p. [in Russian].Bakunov V. S., Balkevich V. L., Guzman I. Ya., Lukin E. S. Workshop on the technology of ceramics and refractories. — Moscow: Stroyizdat, 1972. — 352 p. [in Russian].Wang J., Kong L., Li T., et al. A novel TiAl3/Al2O3 composite coating on γ-TiAl alloy and evaluating the oxidation performance / J. Appl. Surf. Sci. 2016. Vol. 361. P. 90 – 94. DOI: 10.1016/j.apsusc.2015.11.155Wang J., Kong L., Li T., et al. A novel TiAl3/Al2O3 composite coating on γ-TiAl alloy and evaluating the oxidation performance / J. Appl. Surf. Sci. 2016. Vol. 361. P. 90 – 94. DOI: 10.1016/j.apsusc.2015.11.155Bester G., Fähnle M. Interpretation of ab initio total energy results in a chemical language: II. Stability of TiAl3 and ScAl3 / J. Phys. Condens. Matter. 2001. Vol. 13. P. 11551. DOI: 10.1088/0953 – 8984/13/50/314Bester G., Fähnle M. Interpretation of ab initio total energy results in a chemical language: II. Stability of TiAl3 and ScAl3 / J. Phys. Condens. Matter. 2001. Vol. 13. P. 11551. DOI: 10.1088/0953 – 8984/13/50/314

The authors declare that there are no conflicts of interest present.