zldmЗаводская лаборатория. Диагностика материаловIndustrial laboratory. Diagnostics of materials1028-68612588-0187ООО «Издательство «ТЕСТ-ЗЛ»10.26896/1028-6861-2024-90-6-5-14zldm-2223Research ArticleАНАЛИЗ ВЕЩЕСТВАSUBSTANCES ANALYSISСенсорный гранулированный материал на основе импрегнированного композита «сшитый поливиниловый спирт – магнетит» для определения углеводов методом оптической микрометрииA sensory granular material based on impregnated composite «cross-linked polyvinyl alcohol – magnetite» for the determination of carbohydrates by optical micrometryЩемелевИ. С.ShchemelevI. S.

Иван Сергеевич Щемелев,

119991, Москва, Ленинские горы, д. 1, стр. 3.

Ivan S. Shchemelev,

Moscow.

shchemelev_93@mail.ruЗиновьевН. А.Zinov’evN. A.

Николай Андреевич Зиновьев,

119991, Москва, Ленинские горы, д. 1, стр. 3.

Nikolay A. Zinov’ev,

Moscow.

ИвановА. В.IvanovA. V.

Александр Вадимович Иванов, 

119991, Москва, Ленинские горы, д. 1, стр. 3;

119991, Москва, Ленинский проспект, д. 31.

Alexander V. Ivanov,

Moscow.

ФерапонтовН. Б.FerapontovN. B.

Николай Борисович Ферапонтов,

119991, Москва, Ленинские горы, д. 1, стр. 3.

Nikolay B. Ferapontov,

Moscow.

МихеевИ. В.MikheevI. V.

Иван Владимирович Михеев,

119991, Москва, Ленинские горы, д. 1, стр. 3.

Ivan V. Mikheev, 

Moscow.

ГагаринА. Н.GagarinA. N.

Александр Николаевич Гагарин,

119334, Москва, ул. Косыгина, д. 19, стр. 1.

Alexander N. Gagarin, 

Moscow.

Московский государственный университет имени М. В. Ломоносова, Химический факультетРоссияLomonosov Moscow State UniversityRussian FederationМосковский государственный университет имени М. В. Ломоносова, Химический факультет; Институт общей и неорганической химии им. Н. С. Курнакова РАНРоссияLomonosov Moscow State University; Kurnakov Institute of General and Inorganic Chemistry of the RASRussian FederationИнститут геохимии и аналитической химии им. В. И. Вернадского РАНРоссияVernadskii Institute of Geochemistry and Analytical Chemistry of the RASRussian Federation202421062024906514Copyright © Щемелев И.С., Зиновьев Н.А., Иванов А.В., Ферапонтов Н.Б., Михеев И.В., Гагарин А.Н., 20242024Щемелев И.С., Зиновьев Н.А., Иванов А.В., Ферапонтов Н.Б., Михеев И.В., Гагарин А.Н.Shchemelev I.S., Zinov’ev N.A., Ivanov A.V., Ferapontov N.B., Mikheev I.V., Gagarin A.N.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.zldm.ru/jour/article/view/2223

Рассмотрены получение композитного материала «сшитый поливиниловый спирт – магнетит», импрегнированного раствором тетрабората натрия, и его применение в качестве чувствительного элемента для определения углеводов в водных растворах методом оптической микрометрии. Методом ИК-спектроскопии подтверждена химическая структура исследуемого полимера. С помощью кривых намагничивания рассчитано содержание частиц Fe3O4 в гранулах поливинилового спирта (ПВС). Показано, что при pH среды 6,8 внедрение магнетита в гранулы сужает диапазон определяемых содержаний углеводов и снижает чувствительность матрицы ПВС к ним; однако при pH 8,6 наличие частиц Fe3O4 в гранулах не увеличивает предел обнаружения глюкозы и фруктозы (7,9 ммоль/дм3), но позволяет снизить относительные стандартные отклонения их определения до 3 % масс. Сенсорные гранулы с оптимальным содержанием магнетита (1,54 %) апробированы при определении методом оптической микрометрии суммарного содержания углеводов в образцах натуральных сиропов с высоким содержанием фруктозы. Полученные результаты хорошо согласуются с данными, указанными производителями сиропов.

Synthesis and application of a composite material «cross-linked polyvinyl alcohol (PVA) – magnetite» as a sensitive element for the determination of carbohydrates by optical micrometry has been studied. The chemical structure was confirmed by IR-spectroscopy. The content of Fe3O4 in PVA granules was calculated using magnetization curves. It is shown that the introduction of Fe3O4 particles into PVA granules at pH value of buffer solution 6.8 significantly narrows the range of carbohydrate concentrations to be determined and reduces the sensitivity of PVA to them. However, at pH 8.6 the presence of Fe3O4 particles in granules does not affect the metrological characteristics of the glucose and fructose determination (their detection limit equals 7.9 mmol/dm3) but reduces the relative standard deviation of their determination to 3 wt.%. Sensory granules with optimal magnetite content (1.54%) were tested in the determination of total content of glucose and fructose in natural syrups with a high level of fructose by optical micrometry. The results obtained match the accepted reference values specified by the syrup manufacturers.

композитные чувствительные материалыполивиниловый спиртмагнетитметод оптической микрометрииопределение углеводовcomposite sensitive materialspolyvinyl alcoholmagnetiteoptical micrometrycarbohydrates determinationРабота выполнена при финансовой поддержке Минобрнауки России в рамках государственных заданий МГУ (регистрационный номер АААА-А21-121011590089-1) и ИОНХ РАН (регистрационный номер 1021071612841-6-1.4.7).ReferencesShou W., Yang Sh.-T., Wang Y.-L., Guo L.-H. Preparation of noble metal nanoparticles and hydrogel composite materials and their application in analytical chemistry / Chinese J. Anal. Chem. 2021. Vol. 49. N 5. P. 676 – 685. DOI: 10.1016/S1872-2040(21)60097-XShou W., Yang Sh.-T., Wang Y.-L., Guo L.-H. Preparation of noble metal nanoparticles and hydrogel composite materials and their application in analytical chemistry / Chinese J. Anal. Chem. 2021. Vol. 49. N 5. P. 676 – 685. DOI: 10.1016/S1872-2040(21)60097-XLiu Ch., Quan K., Chen J., et al. Chiral metal-organic frameworks and their composites as stationary phases for liquid chromatography chiral separation: a review / J. Chromatogr. A. 2023. Vol. 1700. 464032. DOI: 10.1016/j.chroma.2023.464032Liu Ch., Quan K., Chen J., et al. Chiral metal-organic frameworks and their composites as stationary phases for liquid chromatography chiral separation: a review / J. Chromatogr. A. 2023. Vol. 1700. 464032. DOI: 10.1016/j.chroma.2023.464032Si T., Wang Sh., Zhang H., et al. An alternative strategy to construct uniform MOFs-Grafted silica core-shell composites as mixed-mode stationary phase for chromatography separation / Anal. Chim. Acta. 2021. Vol. 1183. 338942. DOI: 10.1016/j.aca.2021.338942Si T., Wang Sh., Zhang H., et al. An alternative strategy to construct uniform MOFs-Grafted silica core-shell composites as mixed-mode stationary phase for chromatography separation / Anal. Chim. Acta. 2021. Vol. 1183. 338942. DOI: 10.1016/j.aca.2021.338942Prosuntsova D. S., Plodukhin A. Yu., Ananieva I. A., et al. New composite stationary phase for chiral high-performance liquid chromatography / J. Porous Mater. 2021. Vol. 28. N 2. P. 407 – 414. DOI: 10.1007/s10934-020-00985-yProsuntsova D. S., Plodukhin A. Yu., Ananieva I. A., et al. New composite stationary phase for chiral high-performance liquid chromatography / J. Porous Mater. 2021. Vol. 28. N 2. P. 407 – 414. DOI: 10.1007/s10934-020-00985-yProsuntsova D. S., Ananieva I. A., Nesterenko P. N., Shpigun O. A. Microspherical polystyrene-divinylbenzene particles hybridized with eremomycin stabilized gold nanoparticles as a stationary phase for chiral liquid chromatography / Industr. Lab. Mater. Diagn. 2022. Vol. 88. N 12. P. 14 – 20 [in Russian]. DOI: 10.26896/1028-6861-2022-88-12-14-20Prosuntsova D. S., Ananieva I. A., Nesterenko P. N., Shpigun O. A. Microspherical polystyrene-divinylbenzene particles hybridized with eremomycin stabilized gold nanoparticles as a stationary phase for chiral liquid chromatography / Industr. Lab. Mater. Diagn. 2022. Vol. 88. N 12. P. 14 – 20 [in Russian]. DOI: 10.26896/1028-6861-2022-88-12-14-20Amini Sh., Kandeh S. H., Ebrahimzadeh H., Khodayari P. Electrospun composite nanofibers modified with silver nanoparticles for extraction of trace heavy metals from water and rice samples: an highly efficient and reproducible sorbent / Food Chem. 2023. Vol. 420. 136122. DOI: 10.1016/j.foodchem.2023.136122Amini Sh., Kandeh S. H., Ebrahimzadeh H., Khodayari P. Electrospun composite nanofibers modified with silver nanoparticles for extraction of trace heavy metals from water and rice samples: an highly efficient and reproducible sorbent / Food Chem. 2023. Vol. 420. 136122. DOI: 10.1016/j.foodchem.2023.136122Ahmed E. M., Isawi H., Morsy M., et al. Effective nanomembranes from chitosan/PVA blend decorated graphene oxide with gum rosin and silver nanoparticles for removal of heavy metals and microbes from water resources / Surf. Interfaces. 2023. Vol. 39. 102980. DOI: 10.1016/j.surfin.2023.102980Ahmed E. M., Isawi H., Morsy M., et al. Effective nanomembranes from chitosan/PVA blend decorated graphene oxide with gum rosin and silver nanoparticles for removal of heavy metals and microbes from water resources / Surf. Interfaces. 2023. Vol. 39. 102980. DOI: 10.1016/j.surfin.2023.102980Jinadasa K. K., Peña-Vázquez E., Bermejo-Barrera P., et al. New adsorbents based on imprinted polymers and composite nanomaterials for arsenic and mercury screening/speciation: A review / Microchem. J. 2020. Vol. 156. 104886. DOI: 10.1016/j.microc.2020.104886Jinadasa K. K., Peña-Vázquez E., Bermejo-Barrera P., et al. New adsorbents based on imprinted polymers and composite nanomaterials for arsenic and mercury screening/speciation: A review / Microchem. J. 2020. Vol. 156. 104886. DOI: 10.1016/j.microc.2020.104886Hejabri Kandeh S., Amini Sh., Ebrahimzadeh H. PVA/Stevia/MIL-88A@AuNPs composite nanofibers as a novel sorbent for simultaneous extraction of eight agricultural pesticides in food and vegetable samples followed by HPLC-UV analysis / Food Chem. 2022. Vol. 386. 132734. DOI: 10.1016/j.foodchem.2022.132734Hejabri Kandeh S., Amini Sh., Ebrahimzadeh H. PVA/Stevia/MIL-88A@AuNPs composite nanofibers as a novel sorbent for simultaneous extraction of eight agricultural pesticides in food and vegetable samples followed by HPLC-UV analysis / Food Chem. 2022. Vol. 386. 132734. DOI: 10.1016/j.foodchem.2022.132734Alizadeh R., Mashalavi B., Faal A. Ye., Seidi Sh. Development of ultrasound assisted dispersive micro solid phase extraction based on CuO nanoplate-polyaniline composite as a new sorbent for insecticides analysis in wheat samples / Microchem. J. 2021. Vol. 168. 106422. DOI: 10.1016/j.microc.2021.106422Alizadeh R., Mashalavi B., Faal A. Ye., Seidi Sh. Development of ultrasound assisted dispersive micro solid phase extraction based on CuO nanoplate-polyaniline composite as a new sorbent for insecticides analysis in wheat samples / Microchem. J. 2021. Vol. 168. 106422. DOI: 10.1016/j.microc.2021.106422Vosough S., Amini Sh., Ebrahimzadeh H., Kandeh S. H. Application of electrospun composite nanofibers as an efficient sorbent for extraction of pesticides from food samples / J. Chromatogr. A. 2023. Vol. 1687. 463699. DOI: 10.1016/j.chroma.2022.463699Vosough S., Amini Sh., Ebrahimzadeh H., Kandeh S. H. Application of electrospun composite nanofibers as an efficient sorbent for extraction of pesticides from food samples / J. Chromatogr. A. 2023. Vol. 1687. 463699. DOI: 10.1016/j.chroma.2022.463699Jullakan S., Bunkoed O. A nanocomposite adsorbent of metallic copper, polypyrrole, halloysite nanotubes and magnetite nanoparticles for the extraction and enrichment of sulfonamides in milk / J. Chromatogr. B. 2021. Vol. 1180. 122900. DOI: 10.1016/j.jchromb.2021.122900Jullakan S., Bunkoed O. A nanocomposite adsorbent of metallic copper, polypyrrole, halloysite nanotubes and magnetite nanoparticles for the extraction and enrichment of sulfonamides in milk / J. Chromatogr. B. 2021. Vol. 1180. 122900. DOI: 10.1016/j.jchromb.2021.122900You R., Wang H., Wang Ch., et al. Bacterial cellulose loaded with silver nanoparticles as a flexible, stable and sensitive SERS-active substrate for detection of the shellfish toxin DTX-1 / Food Chem. 2023. Vol. 427. 136692. DOI: 10.1016/j.foodchem.2023.136692You R., Wang H., Wang Ch., et al. Bacterial cellulose loaded with silver nanoparticles as a flexible, stable and sensitive SERS-active substrate for detection of the shellfish toxin DTX-1 / Food Chem. 2023. Vol. 427. 136692. DOI: 10.1016/j.foodchem.2023.136692Devasurendra A. M., Palagama D. S. W., Rohanifar A., et al. Solid-phase extraction, quantification, and selective determination of microcystins in water with a gold-polypyrrole nanocomposite sorbent material / J. Chromatogr. A. 2018. Vol. 1560. P. 1 – 9. DOI: 10.1016/j.chroma.2018.04.027Devasurendra A. M., Palagama D. S. W., Rohanifar A., et al. Solid-phase extraction, quantification, and selective determination of microcystins in water with a gold-polypyrrole nanocomposite sorbent material / J. Chromatogr. A. 2018. Vol. 1560. P. 1 – 9. DOI: 10.1016/j.chroma.2018.04.027Devi R., Thakur M., Pundir C. S. Construction and application of an amperometric xanthine biosensor based on zinc oxide nanoparticles — polypirrole composite film / Biosens. Bioelectron. 2011. Vol. 26. N 8. P. 3420 – 3426. DOI: 10.1016/j.bios.2011.01.014Devi R., Thakur M., Pundir C. S. Construction and application of an amperometric xanthine biosensor based on zinc oxide nanoparticles — polypirrole composite film / Biosens. Bioelectron. 2011. Vol. 26. N 8. P. 3420 – 3426. DOI: 10.1016/j.bios.2011.01.014Wang Ya., Tang G., Zhao Ch., et al. Experimental investigation on the physical parameters of ionic polymer metal composites sensors for humidity perception / Sens. Actuators, B. 2021. Vol. 345. 130421. DOI: 10.1016/j.snb.2021.130421Wang Ya., Tang G., Zhao Ch., et al. Experimental investigation on the physical parameters of ionic polymer metal composites sensors for humidity perception / Sens. Actuators, B. 2021. Vol. 345. 130421. DOI: 10.1016/j.snb.2021.130421Gu Yi., Wang Ya., Wu X., et al. Quartz crystal microbalance sensor based on covalent organic framework composite and molecularly imprinted polymer of poly(o-aminothiophenol) with gold nanoparticles for the determination of aflatoxin B1 / Sens. Actuators, B. 2019. Vol. 291. P. 293 – 297. DOI: 10.1016/j.snb.2019.04.092Gu Yi., Wang Ya., Wu X., et al. Quartz crystal microbalance sensor based on covalent organic framework composite and molecularly imprinted polymer of poly(o-aminothiophenol) with gold nanoparticles for the determination of aflatoxin B1 / Sens. Actuators, B. 2019. Vol. 291. P. 293 – 297. DOI: 10.1016/j.snb.2019.04.092Zhizhin K. Yu., Turyshev E. S., Kopytin A. V., et al. Polymer nanocarbon materials as ion-to-electron transducers in solid-contact ion selective electrodes / Nanosystems: Phys. Chem. Math. 2022. Vol. 13. N 6. P. 688 – 697. DOI: 10.17586/2220-8054-2022-13-6-688-697Zhizhin K. Yu., Turyshev E. S., Kopytin A. V., et al. Polymer nanocarbon materials as ion-to-electron transducers in solid-contact ion selective electrodes / Nanosystems: Phys. Chem. Math. 2022. Vol. 13. N 6. P. 688 – 697. DOI: 10.17586/2220-8054-2022-13-6-688-697Shpigun L. K., Isaeva N. A., Suranova M. A. Determination of catecolamines on electrode modified with multiwalled carbon nanotubes / Rus. J. Electrochem. 2014. Vol. 50. N 10. P. 926 – 932. DOI: 10.1134/S1023193514100103Shpigun L. K., Isaeva N. A., Suranova M. A. Determination of catecolamines on electrode modified with multiwalled carbon nanotubes / Rus. J. Electrochem. 2014. Vol. 50. N 10. P. 926 – 932. DOI: 10.1134/S1023193514100103Lu M., Zhu H., Bazuin C. G., et al. Polymer-templated gold nanoparticles on oprical fibers for enhanced-sensitivity localized surface plasmon resonance biosensors / ACS Sens. 2019. Vol. 4. N 3. P. 613 – 622. DOI: 10.1021/acssensors.8b01372Lu M., Zhu H., Bazuin C. G., et al. Polymer-templated gold nanoparticles on oprical fibers for enhanced-sensitivity localized surface plasmon resonance biosensors / ACS Sens. 2019. Vol. 4. N 3. P. 613 – 622. DOI: 10.1021/acssensors.8b01372Mamtmin G., Nizamidin P., Abula R., Yimit A. Composite optical waveguide sensor based on porphyrin@ZnO film for sulfide-gas detection / Chinese J. Anal. Chem. 2023. Vol. 51. N 7. 100260. DOI: 10.1016/j.cjac.2023.100260Mamtmin G., Nizamidin P., Abula R., Yimit A. Composite optical waveguide sensor based on porphyrin@ZnO film for sulfide-gas detection / Chinese J. Anal. Chem. 2023. Vol. 51. N 7. 100260. DOI: 10.1016/j.cjac.2023.100260Yetisen A. K., Butt H., Yun S.-H. Photonic crystal flakes / ACS Sensors. 2016. Vol. 1. N 5. P. 493 – 497. DOI: 10.1021/acssensors.6b00108Yetisen A. K., Butt H., Yun S.-H. Photonic crystal flakes / ACS Sensors. 2016. Vol. 1. N 5. P. 493 – 497. DOI: 10.1021/acssensors.6b00108Kraiskii A. V., Sultanov T. T., Postnikov V. A., Khamidulin A. V. Holographic sensors for diagnostics of solution components / Quant. Electron. 2010. Vol. 40. N 2. P. 178 – 182. DOI: 10.1070/QE2010v040n02ABEH014169Kraiskii A. V., Sultanov T. T., Postnikov V. A., Khamidulin A. V. Holographic sensors for diagnostics of solution components / Quant. Electron. 2010. Vol. 40. N 2. P. 178 – 182. DOI: 10.1070/QE2010v040n02ABEH014169Martinez-Hurtado J. L., Davidson C. A. B., Blyth J., Lowe C. R. Holographic detection of hydrocarbon gases and other volatile compounds / Langmuir. 2010. Vol. 26. N 19. P. 15694 – 15699. DOI: 10.1021/la102693mMartinez-Hurtado J. L., Davidson C. A. B., Blyth J., Lowe C. R. Holographic detection of hydrocarbon gases and other volatile compounds / Langmuir. 2010. Vol. 26. N 19. P. 15694 – 15699. DOI: 10.1021/la102693mTolmacheva V. V., Apyari V. V., Kochuk E. V., Dmitrienko S. G. Magnetic adsorbents based on iron oxide nanoparticles for the extraction and preconcentration of organic compounds / J. Anal. Chem. 2016. Vol. 71. N 4. P. 321 – 338. DOI: 10.1134/S1061934816040079Tolmacheva V. V., Apyari V. V., Kochuk E. V., Dmitrienko S. G. Magnetic adsorbents based on iron oxide nanoparticles for the extraction and preconcentration of organic compounds / J. Anal. Chem. 2016. Vol. 71. N 4. P. 321 – 338. DOI: 10.1134/S1061934816040079Dmitrienko S. G., Apyari V. V., Tolmacheva V. V., et al. Dispersive and magnetic solid-phase extraction of organic compounds: Review of reviews / J. Anal. Chem. 2024. Vol. 79. N 2. P. 105 – 118. DOI: 10.1134/S1061934824020060Dmitrienko S. G., Apyari V. V., Tolmacheva V. V., et al. Dispersive and magnetic solid-phase extraction of organic compounds: Review of reviews / J. Anal. Chem. 2024. Vol. 79. N 2. P. 105 – 118. DOI: 10.1134/S1061934824020060Sánchez-González J., Tabernero M. J., Bermejo A. M., et al. Development of magnetic molecularly imprinted polymers for solid phase extraction of cocaine and metabolites in urine before high performance liquid chromatography — tandem mass spectrometry / Talanta. 2016. Vol. 147. P. 641 – 649. DOI: 10.1016/j.talanta.2015.10.034Sánchez-González J., Tabernero M. J., Bermejo A. M., et al. Development of magnetic molecularly imprinted polymers for solid phase extraction of cocaine and metabolites in urine before high performance liquid chromatography — tandem mass spectrometry / Talanta. 2016. Vol. 147. P. 641 – 649. DOI: 10.1016/j.talanta.2015.10.034Sorribes-Soriano A., Esteve-Turrillas A., Armenta S., et al. Magnetic molecularly imprinted polymers for the selective determination of cocaine by ion mobility spectrometry / J. Chromatogr. A. 2015. Vol. 1545. P. 22 – 31. DOI: 10.1016/j.chroma.2018.02.055Sorribes-Soriano A., Esteve-Turrillas A., Armenta S., et al. Magnetic molecularly imprinted polymers for the selective determination of cocaine by ion mobility spectrometry / J. Chromatogr. A. 2015. Vol. 1545. P. 22 – 31. DOI: 10.1016/j.chroma.2018.02.055Asgharinezhad A. A., Ebrahimzadeh H. Poly(2-aminobenzothiazole)-coated graphene oxide/magnetite nanoparticles composite as an efficient sorbent for determination of non-steroidal anti-inflammatory drugs in urine sample / J. Chromatogr. A. 2016. Vol. 1435. P. 18 – 29. DOI: 10.1016/j.chroma.2016.01.027Asgharinezhad A. A., Ebrahimzadeh H. Poly(2-aminobenzothiazole)-coated graphene oxide/magnetite nanoparticles composite as an efficient sorbent for determination of non-steroidal anti-inflammatory drugs in urine sample / J. Chromatogr. A. 2016. Vol. 1435. P. 18 – 29. DOI: 10.1016/j.chroma.2016.01.027Bagheri H., Afkhami A., Saber-Tehrani M., Khoshsafar H. Preparation and characterization of magnetic nanocomposite of Schiff base/silica/magnetite as a preconcentration phase for the trace determination of heavy metal ions in water, food and biological samples using atomic absorption spectrometry / Talanta. 2012. Vol. 97. P. 87 – 95. DOI: 10.1016/j.talanta.2012.03.066Bagheri H., Afkhami A., Saber-Tehrani M., Khoshsafar H. Preparation and characterization of magnetic nanocomposite of Schiff base/silica/magnetite as a preconcentration phase for the trace determination of heavy metal ions in water, food and biological samples using atomic absorption spectrometry / Talanta. 2012. Vol. 97. P. 87 – 95. DOI: 10.1016/j.talanta.2012.03.066Li Q., Zhuo Yi., You S., et al. Rapid preparation of melamine based magnetic covalent triazine polymers for highly efficient extraction of copper (II), chromium (III) and lead (II) ions from environmental and biological samples / Microchem. J. 2022. Vol. 181. 107698. DOI: 10.1016/j.microc.2022.107698Li Q., Zhuo Yi., You S., et al. Rapid preparation of melamine based magnetic covalent triazine polymers for highly efficient extraction of copper (II), chromium (III) and lead (II) ions from environmental and biological samples / Microchem. J. 2022. Vol. 181. 107698. DOI: 10.1016/j.microc.2022.107698Barzkar M., Ghiasvand A., Safdarian M. A simple and cost-effective synthesis route using itaconic acid to prepare a magnetic ion-imprinted polymer for preconcentration of Pb (II) from aqueous media / Talanta. 2023. Vol. 259. 124501. DOI: 10.1016/j.talanta.2023.124501Barzkar M., Ghiasvand A., Safdarian M. A simple and cost-effective synthesis route using itaconic acid to prepare a magnetic ion-imprinted polymer for preconcentration of Pb (II) from aqueous media / Talanta. 2023. Vol. 259. 124501. DOI: 10.1016/j.talanta.2023.124501Melekhin A. O., Tolmacheva V. V., Goncharov N. O., et al. Rapid multi-residue LC-MS/MS determination of nitrofuran metabolites, nitroimidazoles, amphenicols, and quinolones in honey with ultrasonic-assisted derivatization — magnetic solid-phase extraction / J. Pharm. Biomed. Anal. 2024. Vol. 237. 115764. DOI: 10.1016/j.jpba.2023.115764Melekhin A. O., Tolmacheva V. V., Goncharov N. O., et al. Rapid multi-residue LC-MS/MS determination of nitrofuran metabolites, nitroimidazoles, amphenicols, and quinolones in honey with ultrasonic-assisted derivatization — magnetic solid-phase extraction / J. Pharm. Biomed. Anal. 2024. Vol. 237. 115764. DOI: 10.1016/j.jpba.2023.115764Melekhin A. O., Tolmacheva V. V., Shubina E. G., et al. Determination of nitrofuran metabolites in honey using a new derivatization reagent, magnetic solid-phase extraction and LC-MS/MS / Talanta. 2021. Vol. 230. 122310. DOI: 10.1016/j.talanta.2021.122310Melekhin A. O., Tolmacheva V. V., Shubina E. G., et al. Determination of nitrofuran metabolites in honey using a new derivatization reagent, magnetic solid-phase extraction and LC-MS/MS / Talanta. 2021. Vol. 230. 122310. DOI: 10.1016/j.talanta.2021.122310Ferapontov N. B., Kovaleva S. S., Rubin F. F. Determination of the nature and concentration of solutes using the swelling granule method / J. Anal. Chem. 2007. Vol. 62. N 10. P. 924 – 929. DOI: 10.1134/S1061934807100048Ferapontov N. B., Kovaleva S. S., Rubin F. F. Determination of the nature and concentration of solutes using the swelling granule method / J. Anal. Chem. 2007. Vol. 62. N 10. P. 924 – 929. DOI: 10.1134/S1061934807100048Kudukhova I. G., Rudakov O. B., Rudakova L. V., Ferapontov N. B. A new route for the control of water content in water-alcohol mixtures based on microphotographic measurement of swelling effect of polymer granules / Sorbts. Khromat. Processy. 2010. Vol. 10. N 5. P. 759 – 761 [in Russian].Kudukhova I. G., Rudakov O. B., Rudakova L. V., Ferapontov N. B. A new route for the control of water content in water-alcohol mixtures based on microphotographic measurement of swelling effect of polymer granules / Sorbts. Khromat. Processy. 2010. Vol. 10. N 5. P. 759 – 761 [in Russian].Babayan I. I., Ivanov A. V., Ferapontov N. B., Tokmachev M. G. Using crosslinked polyvinyl alcohol granules for the determination of the composition of mixed electrolyte solutions / J. Anal. Chem. 2019. Vol. 74. N 8. P. 834 – 838. DOI: 10.1134/S1061934819080033Babayan I. I., Ivanov A. V., Ferapontov N. B., Tokmachev M. G. Using crosslinked polyvinyl alcohol granules for the determination of the composition of mixed electrolyte solutions / J. Anal. Chem. 2019. Vol. 74. N 8. P. 834 – 838. DOI: 10.1134/S1061934819080033Karimov Kh. R., Staroverova A. V., Tokmachev M. G., et al. Application of composite polyvinyl alcohol – magnetite for increase of the accuracy of optical micrometry method / Sorbts. Khromat. Processy. 2023. Vol. 23. N 2. P. 216 – 224 [in Russian]. DOI: 10.17308/sorpchrom.2023.23/11145Karimov Kh. R., Staroverova A. V., Tokmachev M. G., et al. Application of composite polyvinyl alcohol – magnetite for increase of the accuracy of optical micrometry method / Sorbts. Khromat. Processy. 2023. Vol. 23. N 2. P. 216 – 224 [in Russian]. DOI: 10.17308/sorpchrom.2023.23/11145Ivanov A. V., Smirnova M. A., Tikhanova O. A., et al. Granulated metamaterial cross-linked polyvinyl alcohol magnetite for use in optical micrometry / Theor. Found. Chem. Eng. 2021. Vol. 55. N 5. P. 1009 – 1014. DOI: 10.1134/S0040579521050067Ivanov A. V., Smirnova M. A., Tikhanova O. A., et al. Granulated metamaterial cross-linked polyvinyl alcohol magnetite for use in optical micrometry / Theor. Found. Chem. Eng. 2021. Vol. 55. N 5. P. 1009 – 1014. DOI: 10.1134/S0040579521050067Shchemelev I. S., Smirnova M. A., Ivanov A. V., Ferapontov N. B. Application of a complex forming impregnated polyvinyl alcohol for the determination of carbohydrates by optical micrometry / Rus. J. Coord. Chem. 2022. Vol. 48. N 10. P. 641 – 646. DOI: 10.1134/S1070328422100050Shchemelev I. S., Smirnova M. A., Ivanov A. V., Ferapontov N. B. Application of a complex forming impregnated polyvinyl alcohol for the determination of carbohydrates by optical micrometry / Rus. J. Coord. Chem. 2022. Vol. 48. N 10. P. 641 – 646. DOI: 10.1134/S1070328422100050Shchemelev I. S., Khasanov D. S., Smirnova M. A., et al. Determination of reducing carbohydrates in natural honey samples by optical micrometry method / Chim. Techno Acta. 2022. Vol. 9. N 4. 20229417. DOI: 10.15826/chimtech.2022.9.4.17Shchemelev I. S., Khasanov D. S., Smirnova M. A., et al. Determination of reducing carbohydrates in natural honey samples by optical micrometry method / Chim. Techno Acta. 2022. Vol. 9. N 4. 20229417. DOI: 10.15826/chimtech.2022.9.4.17Yamskov I. A., Budanov M. V., Davankov V. A. Polyvinyl alcohol hydrophilic carriers for enzyme immobilization / Russ. J. Bioorg. Chem. 1979. Vol. 5. N 11. P. 1728 – 1734 [in Russian].Yamskov I. A., Budanov M. V., Davankov V. A. Polyvinyl alcohol hydrophilic carriers for enzyme immobilization / Russ. J. Bioorg. Chem. 1979. Vol. 5. N 11. P. 1728 – 1734 [in Russian].Gruzdeva A. N., Gorshkov V. I., Gagarin A. N., Ferapontov N. B. Separation of electrolytes by sorption on crosslinked poly(vinyl alcohol) / Russ. J. Phys. Chem. A. 2005. Vol. 79. N 7. P. 1150 – 1152.Gruzdeva A. N., Gorshkov V. I., Gagarin A. N., Ferapontov N. B. Separation of electrolytes by sorption on crosslinked poly(vinyl alcohol) / Russ. J. Phys. Chem. A. 2005. Vol. 79. N 7. P. 1150 – 1152.Bellamy L. J. The infra-red spectra of complex molecules. — London: Chapman and Hall; New York: Willey, 1975. — 433 p.Bellamy L. J. The infra-red spectra of complex molecules. — London: Chapman and Hall; New York: Willey, 1975. — 433 p.Allayarov S. R., Korchagin D. V., Allayarova U. Y., et al. Influence of gamma irradiation on the IR spectra and acute toxicity of polyvinyl alcohol / High Energy Chem. 2021. Vol. 55. N 1. P. 40 – 46. DOI: 10.1134/S0018143921010021Allayarov S. R., Korchagin D. V., Allayarova U. Y., et al. Influence of gamma irradiation on the IR spectra and acute toxicity of polyvinyl alcohol / High Energy Chem. 2021. Vol. 55. N 1. P. 40 – 46. DOI: 10.1134/S0018143921010021Ivanov A. V., Ferapontov N. B., Gagarin A. N., et al. Metamaterials based on polyvinyl alcohol with metal or metal oxide particles: synthesis and study by nondestructive physical methods / Theor. Found. Chem. Eng. 2020. Vol. 54. N 5. P. 1068 – 1073. DOI: 10.1134/S0040579520050115Ivanov A. V., Ferapontov N. B., Gagarin A. N., et al. Metamaterials based on polyvinyl alcohol with metal or metal oxide particles: synthesis and study by nondestructive physical methods / Theor. Found. Chem. Eng. 2020. Vol. 54. N 5. P. 1068 – 1073. DOI: 10.1134/S0040579520050115Kostishin V. G., Nuriev A. V., Ostafiychuk B. K., Moklyak V. V. Mössbauer studies of magnetic polymer nanocomposites based on magnetite and polyvinyl alcohol / Izv. Vuzov. Mater. Élektron. Tekhn. 2013. N 4. P. 24 – 29 [in Russian].Kostishin V. G., Nuriev A. V., Ostafiychuk B. K., Moklyak V. V. Mössbauer studies of magnetic polymer nanocomposites based on magnetite and polyvinyl alcohol / Izv. Vuzov. Mater. Élektron. Tekhn. 2013. N 4. P. 24 – 29 [in Russian].Verchere J. F., Hlaibi M. Stability constants of borate complexes of oligosaccharides / Polyhedron. 1987. Vol. 6. N 6. P. 1415 – 1420. DOI: 10.1016/S0277-5387(00)80903-1Verchere J. F., Hlaibi M. Stability constants of borate complexes of oligosaccharides / Polyhedron. 1987. Vol. 6. N 6. P. 1415 – 1420. DOI: 10.1016/S0277-5387(00)80903-1Shchemelev I. S., Zinov’ev T. V., Ivanov A. V., Ferapontov N. B. Digital colorometric analysis of aqueous and water-organic systems using hydrophilic composite films «crosslinked polyvinyl alcohol – magnetite» / J. Anal. Chem. 2024. Vol. 79 [in press].Shchemelev I. S., Zinov’ev T. V., Ivanov A. V., Ferapontov N. B. Digital colorometric analysis of aqueous and water-organic systems using hydrophilic composite films «crosslinked polyvinyl alcohol – magnetite» / J. Anal. Chem. 2024. Vol. 79 [in press].

The authors declare that there are no conflicts of interest present.