Methods for identification of Bi (v) and unusual oxygen valence states in BaBiO3 and superconducting oxides of K - Ba - Bi - O system
https://doi.org/10.26896/1028-6861-2019-85-8-16-28
Abstract
A radically different behavior of oxides — BaBiO3 and superconducting KnBamBim+nOy (n = 1, 2, 3; m = 1, 3, 4, 5) — and BaO2 peroxide is observed in reactions of hydrolysis and acid dissolution. Chemical tests and potentiometric analysis did not reveal peroxide-ions present in BaBiO3 and KnBamBim+nOy, as well as in the products obtained by oxide treatment with water, alkali and acids. Most probably this indicates to the absence of unusual valence states (UVS) of oxygen in the form of peroxide- and superoxide-ions in the structure of oxides under study. Data of potentiometric titration (PT) also proved the absence of oxygen UVS and bismuth in the oxidation state of < + 3 in superconducting KnBamBim+nOy oxides. A number of agents (Mn (II), Cr (III), Cu (II), Ce (III) salts, Arnold’s base, methyl red, chromazurol S, arsenazo III, indigo carmine, and thoron) are revealed which provide Bi (V) detection in BaBiO3 and KnBamBim+nOy. An experimentally observed behavior of the oxides in chemical reactions regarding agents-reductants is attributed to Bi (V) present in their structure which is much stronger oxidizer compared to peroxide dioxygen.
About the Author
N. V. Barkovskii
Institute of Solid State Physics of Russian Academy of Sciences
Russian Federation
Russian Federation
Nikolay V Barkovskii.
2 Akademika Osipyana st., Chernogolovka, Moscow oblast’, 142432.
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Review
For citations:
Barkovskii N.V. Methods for identification of Bi (v) and unusual oxygen valence states in BaBiO3 and superconducting oxides of K - Ba - Bi - O system. Industrial laboratory. Diagnostics of materials. 2019;85(8):16-28. (In Russ.) https://doi.org/10.26896/1028-6861-2019-85-8-16-28
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