Determination of Semivolatile Hydrocarbon Fuels in Plants by Gas Chromatography-Mass Spectrometry with Headspace Analysis of the Extract
Abstract
Anew approach to determination of semi-volatile hydrocarbon fuels in plants grown on the soils contaminated by the aforementioned fuel is developed on the example of aviation kerosene. The method is based on ultrasonic methanol pre-extraction of the analyzed compounds followed by static headspace analysis and gas chromatography-mass spectrometry determination. Chromatograms were registered in selected ion monitoring mode (SIM), m/z 57 and 142. The calculated detection limit for aviation kerosene is 1 mg/kg of dry weight of green plants, the detectable concentrations range within 3 - 500 mg/kg of dry weight.
About the Authors
T. A. BolotnikRussian Federation
S. D. Jarcev
Russian Federation
A. D. Smolenkov
Russian Federation
P. P. Krechetov
Russian Federation
O. A. Shpigun
Московский государственный университет имени М. В. Ломоносова, Москва, Россия
Russian Federation
Russian Federation
References
1. Королева Т. В., Кондратьев А. Д., Кречетов П. П. и др. Совершенствование экологических характеристик ракетнокосмической техники и мониторинг ее воздействия на окружающую среду / Экология и промышленность России. 2015. Т. 19. №6. С. 17-23.
2. Fladung N. Optimization of automated solid-phase extraction for quantitation of polycyclic aromatic hydrocarbons in aqueous media by high-performance liquid chromatography-UV detection / J. Chromatogr. A. 1995. Vol. 692. N 1 - 2. P. 21 - 26.
3. Szolar O. H. J., Rost H., Hirmann D., Hasinger M., Braun R., Loibner A. P. Behavior of PAHs during cold storage of historically contaminated soil samples / Chemosphere. 2002. Vol. 49. N 10. P. 1239- 1246.
4. Letellier M., Budzinski H., Bellocq J., Connan J. Focused microwave-assisted extraction of polycyclic aromatic hydrocarbons and alkanes from sediments and source rocks / Org. Geochem. 1999. Vol. 30. N 11. P. 1353 - 1365.
5. Northcott G. L., Jones K. C. Experimental approaches and analytical techniques for determining organic compound bound residues in soil and sediment / Environ. Pollut. 2000. Vol. 108. N 1. P. 19-43.
6. Болотник Т. А., Смоленков А. Д., Ярцев С. Д., Шпигун О. А. Применение метода газовой хромато-масс-спектрометрии с предварительной дисперсионной жидкостно-жидкостной микроэкстракцией для определения низких содержаний ракетных керосинов в воде / Заводская лаборатория. Диагностика материалов. 2015. Т. 81. №1. Ч. I. С. 6 - 12.
7. Meudec A., Dussauze J., Deslandes E., Poupart N. Evidence for bioaccumulation of PAHs within internal shoot tissues by a halophytic plant artificially exposed to petroleumpolluted sediments / Chemosphere. 2006. Vol. 65. P. 474 - 481.
8. Meudec A., Dussauze J., Jourdin M., Deslandes E., Poupart N. Gas chorolatographic-mass spectrometric method for polycyclic aromatic hydrocarbon analysis in plant biota / J. Chromatogr. A. 2006. Vol. 1108. P. 240 - 247.
9. Dugay A., Herrenknecht C., Czok M., Guyon F., Pages N. New procedure for selective extraction of polycyclic aromatic hydrocarbons in plants for gas chromatographic-mass spectro-metric analysis / J. Chromatogr. A. 2002. Vol. 958. P. 1 - 7.
10. Apostolopoulou M.-V., Monteyne E., Krikonis K., Pavlopoulos K., Roose P., Dehairs F. Monitoring polycyclic aromatic hydrocarbons in the Northeast Aegean Sea using Posidonia oceanica seagrass and synthetic passive samplers / Mar. Pollut. Bull. 2014. Vol. 87. P. 338 - 344.
11. Болотник Т. А., Смоленков А. Д., Смирнов Р. С., Шпигун О. А. Определение ракетных керосинов в почвах методом статического парофазного анализа в сочетании с газовой хромато-масс-спектрометрией / Вестн. Моск. ун-та. 2015. Т. 56. №4. С. 212-220
Review
For citations:
Bolotnik T.A., Jarcev S.D., Smolenkov A.D., Krechetov P.P., Shpigun O.A. Determination of Semivolatile Hydrocarbon Fuels in Plants by Gas Chromatography-Mass Spectrometry with Headspace Analysis of the Extract. Industrial laboratory. Diagnostics of materials. 2015;81(10):5-10. (In Russ.)
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