X-RAY FLUORESCENT DETERMINATION OF TITANIUM, ZIRCONIUM, AND CHROMIUM IN TITANIUM-ZIRCONIUM SANDS OF THE BESHPAGIRSKOE DEPOSIT
https://doi.org/10.26896/1028-6861-2022-88-ll-22-26
Abstract
Gaining current information about the chemical composition of samples from different areas of the deposit during geological exploration necessitates the use of methods of rapid analysis, most often X-ray fluorescence analysis in combination with a method of external standard and its modifications. The existing certified methods assume the construction of calibration characteristics using reference standards. We propose to use a rapid method of X-ray fluorescence analysis (XRF) in aversion of the method of fundamental parameters to determine non-ferrous metals in the samples of titanium-zirconium sands of the Beshpagirskoye deposit and specified conditions of analysis. It is shown that when using the method of fundamental parameters, the accuracy indicators are highly competitive with the indicators obtained by the certified method.
About the Authors
Y. V. Kuminova
National University of Science and Technology "MISIS"
Russian Federation
Russian Federation
Yaroslava V Kuminova
119049, Moscow, Leninskii prosp., 4
V. A. Filichkina
National University of Science and Technology "MISIS"
Russian Federation
Russian Federation
Vera A. Filichkina
119049, Moscow, Leninskii prosp., 4
M. N. Filippov
Kurnakov Institute of General and Inorganic Chemistry
Russian Federation
Russian Federation
Mikhail N. Filippov
119991, Moscow, Leninskii prosp., 31
A. S. Kozlov
National University of Science and Technology "MISIS"
Russian Federation
Russian Federation
Alexander S. Kozlov
119049, Moscow, Leninskii prosp., 4
References
1. Chefranova А. V, Lalomov А. V, Borisovsky S. В., et al. Geochemical features of typomorphic metamorphic minerals of the Beshpagir deposit of rare metal-titanium placers / Akt. Probl. Gum. Estestv. Nauk, 2015. Vol. 1. N 10. P 46-51 [in Russian].
2. Bykhovsky L. Z., Vasiliev А. Т., Zabirko A. G. On the project for the development of the Beshpagir complex placer raremetal deposit / Mineral Res. Ross. Ekon. Upravl. 2010. N 2. P 68-75 [in Russian].
3. Veremeeva L. I. Ti-Zr placers in the south of Russia: structural-geomorphological and mineralogical-technological aspects / Razved. Okhrana Nedr. 2011. N6 . P44-5 1 [in Russian].
4. Kremenetsky A. A., Veremeeva L. I., Arkhipova N. A., et al. Economic model of rational subsoil use on the example of the Stavropol Ti-Zr alluvial area / Razved. Okhrana Nedr. 2006. N 9-10. P 13-26 [in Russian].
5. Sporykhina L. V, Vasiliev А. Т., Bykhovskii L. Z., et al. On the issue of improving the quality assessment of ore sands of titanium-bearing (titanium-containing) placers / Razved. Okhrana Nedr. 2016. N 2. P 70-76 [in Russian].
6. X-ray quantitative phase analysis (RKFA) of black concentrates from ore (Ti-Zr) sands (on the example of the Beshpagir deposit). Instruction No. 54 NSOMMI. — Moscow: VIMS, 2005. — 19 p. [in Russian].
7. Meftah N., Mahboub M. S. Spectroscopic characterization of sands dunes minerals of El-Oued (Notheast Algerian Sahara) by FTIR, XRF and XRD analyses / Silicon. 2020. Vol. 12. N 1. P 147-153. DOI:10.1007/sl2633-019-00109-5
8. Raneri S., Botto A., Campanella В., et al. Increasing resolution in chemical mapping of geomaterials: From X-ray fluorescence to laser-induced breakdown spectroscopy / Spectrochim. Acta. Part B. 2022. Vol. 194. 106482. DOI:10.1016/j.sab.2022.106482
9. Fazal A. G., Shah E, Miraj M. A., et al. Geochemical Analysis of Cretaceous Shales from the Hazara Basin, Pakistan: Provenance Signatures and Paleo-Weathering Conditions / J. Mar. Sci. Eng. 2022. Vol. 10. N 6. P 800. DOI:10.3390/jmsel0060800
10. NSAM No. 496-RS. Determination of the mass fraction of titanium, vanadium, iron and zirconium in rocks, ores and products of their processing by X-ray spectral fluorescence method. — Moscow: VIMS, 2015 [in Russian].
11. NSOMTI No. 102. Selection of technological samples during geological exploration for ore minerals. — Moscow: VIMS, 2014 [in Russian].
12. Borkhodoev V. Ya. X-ray fluorescence analysis of rocks by the method of fundamental parameters. — Magadan: SVKNII FEB RAN, 1999. — 279 p. [in Russian].
13. Mantler M., Kawahara N. How accurate are modern fundamental parameter methods? / Rigaku J. 2004. Vol. 21. N 2. P17-25 .
14. Beckhoff В., KanngieBer В., Langhoff N., et al., eds. Handbook of Practical X-Ray Fluorescence Analysis. — Berlin - Heidelberg: Springer-Verlag, 2006. — 863 p.
15. RMG 61-2010. State system for ensuring the uniformity of measurements. Indicators of accuracy, correctness, precision of methods of quantitative chemical analysis. Assessment methods. — Moscow: Standartinform, 2013. — 58 p. [in Russian].
Review
For citations:
Kuminova Y.V., Filichkina V.A., Filippov M.N., Kozlov A.S. X-RAY FLUORESCENT DETERMINATION OF TITANIUM, ZIRCONIUM, AND CHROMIUM IN TITANIUM-ZIRCONIUM SANDS OF THE BESHPAGIRSKOE DEPOSIT. Industrial laboratory. Diagnostics of materials. 2022;88(11):22-26. (In Russ.) https://doi.org/10.26896/1028-6861-2022-88-ll-22-26
Views:
481
Email this article 