Preview

Industrial laboratory. Diagnostics of materials

Advanced search

Dependence of the hardness of WC - Co alloys on the character of the distribution of WC grains in size

https://doi.org/10.26896/1028-6861-2023-89-2-I-45-49

Abstract

The paper presents the results of studying the dependence of the hardness of WC - Co alloy with a Co content of 10 wt.% on the character of the size distribution of WC grains. An equivalent diameter of the circle with an area matching the cross-section area of the grain was chosen as a grain size of the carbide phase. The WC grain sizes were averaged over their number, area and volume. It is shown that for the alloys with a narrow WC grain size distribution the hardness of the alloys as function of the average grain size follows the Hall - Petch relation. As for a wide distribution, a deviation from this function is observed. It is shown that the use of the area-averaged WC grain size enables description of the hardness as a function of the grain size via a unified Hall - Petch equation, regardless of the nature of the grain size distribution. In this case, the average scatter of hardness values around the trend line does not exceed 12 HV. The use of the volume-averaged grain size in description of the hardness dependence results in practice in a large scatter from the regression line, which is attributed to the error in determination of the content of coarse and very coarse grains, when one needs to measure significantly larger number of grains, as compared to averaging over the area. The results obtained may be used in analysis of single-phase and two-phase materials with grain size distributions with a varying width.

About the Authors

M. V. Vasilyeva
Virial Ltd.
Russian Federation

Maria V. Vasilyeva

27, prosp. Engelsa, St. Petersburg, 194156



V. A. Pesin
Virial Ltd.
Russian Federation

Vadim A. Pesin

27, prosp. Engelsa, St. Petersburg, 194156



A. S. Osmakov
Virial Ltd.
Russian Federation

Andrey S. Osmakov

27, prosp. Engelsa, St. Petersburg, 194156



A. I. Shamshurin
Peter the Great St. Petersburg Polytechnic University
Russian Federation

Alexey I. Shamshurin

29, Polytechnicheskaya ul., St. Petersburg, 195251



References

1. Vornberger A., Picker Т., Potschke J., et al. Influence of cemented carbide composition on cutting temperatures and corresponding hot hardnesses / Mater. 2020. Vol. 13. N 20. E 4571. DOI: 10.3390/mal3204571

2. Vornberger A., Potschke J., Gestrich Т., et al. Influence of microstructure on hardness and thermal conductivity of hardmetals / J. Refract. Met. Hard Mater. 2020. Vol. 88. E 105170. DOI: 10.1016/j.ijrmhm.2019.105170

3. Lee H., Gurland J. Hardness and deformation of cemented tungsten carbide / Mater. Sci. Eng. 1978. Vol. 33. N 1. E 125 -133. DOI: 10.1016/0025-5416(78)90163-5

4. Roebuck B. Extrapolating hardness-structure property maps in WC/Co hardmetals / J. Refract. Met. Hard Mater. 2006. Vol. 24. N 1 - 2. E 101 - 108. DOI: 10.1016/j.ijrmhm.2005.04.021

5. Kresse Т., Meinhard D., Bernthaler Т., Schneider G. Hardness of WC-Co hard metals: preparation, quantitative microstructure analysis, structure-property relationship and modelling / J. Refract. Met. Hard Mater. 2018. Vol. 75. E 287 - 293. DOI: 10.1016/j.ijrmhm.2018.05.003

6. Lu Z., Du J., Sun Y., et al. Effect of ultrafine WC contents on the microstructures, mechanical properties and wear resistances of regenerated coarse grained WC-lOCo cemented carbides / J. Refract. Met. Hard Mater. 2021. Vol. 97. E 105516. DOI: 10.1016/j.ijrmhm.2021.105516

7. Miiller D., Konyashin I., Farag S., et al. WC coarsening in cemented carbides during sintering. Fart I: The influence of WC grain size and grain size distribution / J. Refract. Met. Hard Mater. 2022. Vol. 102. E 105714. DOI: 10.1016/j.ijrmhm.2021.105714

8. Potschke J., Sauberlich Т., Vornberger A., Meese-Marktscheffel J. Solid state sintered nanoscaled hardmetals and their properties / J. Refract. Met. Hard Mater. 2018. Vol. 72. E 45 - 50. DOI: 10.1016/j.ijrmhm.2017.12.008

9. Cao R., Lin C., Xie X., Lin Z. Microstructure and mechanical properties of WC-Co-based cemented carbide with bimodal WC grain size distribution / Rare Met. 2018. Vol. 37. E 1 - 7. DOI: 10.1007/S12598-018-1025-Y

10. Garcia J., Collado Cipres V, Blomqvist A., Kaplan B. Cemented carbide microstructures: A review / J. Refract. Met. Hard Mater. 2019. Vol. 80. E 40 - 68. DOI: 10.1016/j.ijrmhm.2018.12.004

11. Roebuck В., Gee M., Bennett E. Modeling hardness variations in WC/Co hardmetals with a wide grain size distribution / In: Froc. Europ. Conf. Advan. Hard. Mater. Froduct. — Turin: Flenum Fress, 1999. E 221 - 228.

12. Engqvist H., Uhrenius B. Determination of the average grain size of cemented carbides / J. Refract. Met. Hard Mater. 2003. Vol. 21. N 1 - 2. E 31 - 35. DOI:10.1016/S0263-4368(03)00005-2

13. Allen T. Farticle size measurement. — Chapman and Hall, 1990. — 832 p. DOI: 10.1007/978-94-009-0417-0

14. Bashkov O. V, Kim V A., Popkova A. A. Technique for digital image processing of the microstructure of aluminum alloys in the MATLAB / Zavod. Lab. Diagn. Mater. 2013. Vol. 79. N 10. E 34-3 9 [in Russian].

15. Kim V A., Belova N. V, Zolotareva S. V Quantitative indicators of the structural organization of polycrystalline materials / Zavod. Lab. Diagn. Mater. 2014. Vol. 80. N 4. E 43 - 46 [in Russian].

16. Tarrago J. M., Coureaux D., Torres Y., et al. Implementation of an effective time-saving two-stage methodology for microstructural characterization of cemented carbides / J. Refract. Met. Hard Mater. 2016. Vol. 55. E 80 - 86. DOI: 10.1016/j.ijrmhm.2015.10.006

17. Podor R., Le Goff X., Lautru J., et al. SEraMic: a semi-automatic method for the segmentation of grain boundaries / J. Eur. Ceram. Soc. 2021. Vol. 41. N 10. E 5349 - 5358. DOI: 10.1016/j.jeurceramsoc.2021.03.062

18. Bankole S., Buckman J., Stow D., Lever H. Grain-size analysis of mudrocks: a new semi-automated method from SEM images / J. Fet. Sci. Eng. 2019. Vol. 174. E 244 - 256. DOI: 10.1016/j.petrol.2018.11.027

19. Liu J., Dai Q., Chen J., et al. The two dimensional microstructure characterization of cemented carbides with an automatic image analysis process / Ceram. Int. 2017. Vol. 43. N 17. E 14865 - 14872. DOI: 10.1016/j.ceramint.2017.08.002


Review

For citations:


Vasilyeva M.V., Pesin V.A., Osmakov A.S., Shamshurin A.I. Dependence of the hardness of WC - Co alloys on the character of the distribution of WC grains in size. Industrial laboratory. Diagnostics of materials. 2023;89(2(I)):45-49. (In Russ.) https://doi.org/10.26896/1028-6861-2023-89-2-I-45-49

Views: 426


ISSN 1028-6861 (Print)
ISSN 2588-0187 (Online)