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EXPRESS DETERMINATION OF EPOXY GROUP IN ORGANIC COMPOUNDS AND EPOXIDE RESINS USING POTENTIOMETRIC ARGENTOMETRIC TITRATION

https://doi.org/10.26896/1028-6861-2017-83-11-26-28

Abstract

A possibility of using certain salts of hydrohalic acids as a source of hydrogen halide in an anhydrous medium for determination of epoxide groups is studied. The reagents based on NaBr, LiJ, KJ, KCl in acetate solution of perchloric acid are proposed for potentiometric determination of epoxy groups in organic compounds and epoxy resins.

 

About the Authors

I. V. Karandi
Институт элементоорганических соединений им. А. Н. Несмеянова РАН, Москва
Russian Federation


A. G. Buyanovskaya
Институт элементоорганических соединений им. А. Н. Несмеянова РАН, Москва
Russian Federation


L. N. Bulatnikova
Институт элементоорганических соединений им. А. Н. Несмеянова РАН, Москва
Russian Federation


References

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3. Evtuschenko Yu. M., Ivanov V. M., Zaitsev B. E. Determination of epoxide and hydroxyl groups in epoxide resins by IR-spectrometry J. Anal. Chem. 2003. Vol. 58. N 4. P. 347 – 350.

4. Duobinis N. K., Kolodzeikis V. S., Zhemaitaitis A. N., et al. Argentometric method for epoxy groups content determination in the presence of organic bases Zh. Analit. Khimii. 1976. Vol. 31. N 5. P. 1026 – 1027 [in Russian].

5. Vostroknutova E. V., Golik V. M., Saprygin A. V., Yaburov M. A. Epoxy groups mass-fraction determination in epoxy resins ED-16 and ED-20 bynear infrared spectroscopy Analit. Kontrol’. 2011. Vol. 15. N 4. P. 462 – 469 [in Russian].

6. Kreshkov A. P. Analitical chemistry of nonaqueous solutions. — Moscow: Khimiya, 1982. — 256 p. [in Russian].

7. Kreshkov A. P., Bykova L. N., Kazaryan N. A. Acid-base titration in nonaqueous media. — Moscow: Khimiya, 1967. — 192 p. [in Russian].


Review

For citations:


Karandi I.V., Buyanovskaya A.G., Bulatnikova L.N. EXPRESS DETERMINATION OF EPOXY GROUP IN ORGANIC COMPOUNDS AND EPOXIDE RESINS USING POTENTIOMETRIC ARGENTOMETRIC TITRATION. Industrial laboratory. Diagnostics of materials. 2017;83(11):26-28. (In Russ.) https://doi.org/10.26896/1028-6861-2017-83-11-26-28

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ISSN 1028-6861 (Print)
ISSN 2588-0187 (Online)