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Study of the effect of electrolyte composition on adhesion and other properties of a coating-base system

https://doi.org/10.26896/1028-6861-2021-87-10-34-39

Abstract

Aluminum alloys with electroplated coatings and copper plated in particular gained multiple applications. However, pre-zincate treatment often fails to provide the desired adhesion of the coating. We present the results of studying the effect of the electrolyte composition on the adhesion and other properties of the coating-base system. It is shown that an electrolyte with a reduced content of sulfuric and phosphoric acids can be used for anodizing and the oxide films formed during anodizing are stable in the usual copper-plating sulfuric acid electrolyte which eliminates contact exchange and increases adhesion. The use of a modern scratch-test method provides numerical determination of the values of adhesion of copper coatings. The adhesion value depends on the surface porosity of the oxide film and on the type of anodized alloys. The results can be used to improve the technology of applying copper coatings, both as an independent coating and as an underlayer in multilayer coatings.

About the Authors

T. I. Devyatkina
R. E. Alekseev Nizhny Novgorod State Technical University
Russian Federation

Tatiana I. Devyatkina

24, ul. Minina, Nizhny Novgorod, 603950



E. S. Belyaev
R. E. Alekseev Nizhny Novgorod State Technical University
Russian Federation

Evgeny S. Belyaev

24, ul. Minina, Nizhny Novgorod, 603950



V. V. Rogozhin
R. E. Alekseev Nizhny Novgorod State Technical University
Russian Federation

Vyacheslav V. Rogozhin

24, ul. Minina, Nizhny Novgorod, 603950



M. V. Maksimov
Central Research Institute «Burevestnik»
Russian Federation

Maksim V. Maksimov

1A, Sormovskoe sh., Nizhny Novgorod, 603950



References

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Review

For citations:


Devyatkina T.I., Belyaev E.S., Rogozhin V.V., Maksimov M.V. Study of the effect of electrolyte composition on adhesion and other properties of a coating-base system. Industrial laboratory. Diagnostics of materials. 2021;87(10):34-39. (In Russ.) https://doi.org/10.26896/1028-6861-2021-87-10-34-39

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ISSN 1028-6861 (Print)
ISSN 2588-0187 (Online)