A new atomic-emission spectrometer Grand-2000
https://doi.org/10.26896/1028-6861-2022-88-1-II-27-33
Abstract
The design of a Grand-2000 atomic emission spectrometer is considered. The optical efficiency and spectral resolution of a Grand-2000 spectrometer are compared with the corresponding characteristics of a Grand spectrometer with multi-element emission spectrum analyzers based on BLPP-2000 and BLPP-4000 photodetector arrays. The optical efficiencies are compared using the ratio of spectral line intensities recorded on the two spectrometers using the same types of photodetectors. The resolution of the spectrometers (FWHM of the spectral line) is measured using different types of photodetectors. It is shown that, when using BLPP-4000 photodetectors, the resolution of a Grand-2000 spectrometer is twice as large (4 pm), compared to a Grand spectrometer. The optical efficiency of a Grand-2000 spectrometer is 3 – 8 times lower, depending on the wavelength. It is also shown that a Grand-2000 spectrometer with BLPP-2000 photodetector arrays has better optical efficiency in the short-wavelength region compared to a Grand spectrometer with BLPP-4000 photodetector arrays at the same values of the spectral resolution.
About the Authors
A. A. DzyubaRussian Federation
Anatoly A. Dzyuba
630090, Novosibirsk, prosp. Akademika Koptyuga, 1
630090, Novosibirsk, prosp. Akademika Koptyuga, 1-100
V. A. Labusov
Russian Federation
Vladimir A. Labusov
630090, Novosibirsk, prosp. Akademika Koptyuga, 1
630090, Novosibirsk, prosp. Akademika Koptyuga, 1-100
630073, Novosibirsk, prosp. K. Marksa, 20
I. A. Zarubin
Russian Federation
Igor A. Zarubin
630090, Novosibirsk, prosp. Akademika Koptyuga, 1
630090, Novosibirsk, prosp. Akademika Koptyuga, 1-100
630073, Novosibirsk, prosp. K. Marksa, 20
References
1. Balandina N. P., Zakharova M. L. New Applications of a Three-Phase Arc and a MAES Analyzerfor Spectral Analysis of Rocks / Zavod. Lab. Diagn. Mater. 2017. Vol. 83. N 1. Part II. P. 31 – 34 [in Russian]. DOI:10.26896/1028-6861-2018-83-1-II-31-34
2. Miroshnikova L. K., Semenyakina N. V., Fillipova N. E., Sharov S. A. Distribution of yttrium and ytterbium in the rocks of the Norilsk region / Nauch. Vestn. Arktiki. 2020. N 9. P. 44 – 49 [in Russian].
3. Apolitsky V. N. Direct integral-scintillation atomic emission spectral analysis of powder samples / Zavod. Lab. Diagn. Mater. 2010. Vol. 76. N 2. P. 3 – 9 [in Russian].
4. Raikhbaum Ya. D., Malykh V. D., Luzhkova M. A. Scintillation method for spectral analysis of tantalum and niobium in ores / Zavod. Lab. Diagn. Mater. 1963. Vol. 6. P. 677 – 680 [in Russian].
5. Prokopchuk S. I. Scintillation spectral analysis in geology. — Irkutsk: Izd. Inst. Geokhimii SO RAN, 1994. — 64 p. [in Russian].
6. Dzyuba A. A., Labusov V. A., Vasil’eva I. A., et al. Analytical capabilities of «Grand-Potok» spectral system for the scintillation determination of gold and silver in geological samples / Analit. Kontrol’. 2017. Vol. 21. N 1. P. 6 – 15 [in Russian]. DOI:10.15826/analitika.2017.21.1.001
7. Vasil’eva I. E., Shabanova E. V., Goryacheva E. M., et al. Determination of Precious Metals in Geological Samples from Four Gold Ore Deposits of the North-East of Russia / J. Anal. Chem. 2018. Vol. 73. N 6. P. 539 – 550. DOI:10.1134/S1061934818040123
8. Vasil’eva I. E., Shabanova E. V., Goryacheva E. M., et al. Noble metals in black shales of the Sukhoi Log gold deposit (East Siberia): evidence from scintillation arc atomic-emission spectrometry / Rus. Geol. Geophys. 2018. Vol. 59. N 8. P. 997 – 1009. DOI:10.1016/j.rgg.2018.07.019
9. Zayakina S. B., Lesnov F. P., Anoshin G. N., Balukhtin A. V. Capabilities of a «Grand-Potok» System for Atomic-Emission Determination of Noble Metals in the Samples from Hydrotherms near the Volcanoes of the Kuril Islands / Zavod. Lab. Diagn. Mater. 2015. Vol. 81. N 1. Part II. P. 38 – 41 [in Russian].
10. Shavekin A. S., Kuptsov A. V., Zayakina S. B., Anoshin G. N. Comparison of the Results of Scintillation Atomic Emission Analysis Obtained on Spectral System «Potok» and a Two-Jet Arc Plasmatron «Fakel» / Zavod. Lab. Diagn. Mater. 2017. Vol. 83. N 1. Part II. P. 97 – 100 [in Russian]. DOI:10.26896/1028-6861-2018-83-1-II-97-100
11. Shevelev G. A., Vasilenko L. I., Kamenskaya E. N., et al. Noble and Rare Metals in Some Coal Deposits of Kazakhstan / Zavod. Lab. Diagn. Mater. 2019. Vol. 85. N 1. Part II. P. 38 – 44 [in Russian]. DOI:10.26896/1028-6861-2019-85-1-II-38-44
12. Babin S. A., Selyunin D. O., Labusov V. A. High-Speed Multichannel MAES Analyzers Based on BLPP-2000 and BLPP-4000 Photodetector Arrays / Inorg. Mater. 2020. Vol. 56. N 14. P. 1431 – 1435. DOI:10.1134/S0020168520140022
13. Peisakhson I. V. Optics of spectral instruments. — Leningrad: Mashinostroenie, 1975 — 312 p. [in Russian].
14. Shabanova E. V., Bus’ko A. E., Vasil’eva I. E. Scintillation arc atomic emission analysis of powder samples using MAES with high temporal resolution / Zavod. Lab. Diagn. Mater. 2012. Vol. 78. N 1. Part II. P. 24 – 33 [in Russian].
15. Dzyuba A. A., Labusov V. A., Babin S. A. Testing of MAES analyzers with BLPP-2000 and BLPP-4000 photodetector linear arrays in a «GRAND-POTOK» spectral system / Analit. Kontrol’. 2019. Vol. 23. N 1. P. 35 – 42 [in Russian]. DOI:10.15826/analitika.2019.23.1.005
16. Labusov V. A., Put’makov A. N., Zarubin I. A., Garanin V. G. New multichannel optical spectrometers based on MAES analyzers / Zavod. Lab. Diagn. Mater. 2012. Vol. 78. N 1. Part II. P. 7 – 13 [in Russian].
17. Shabanova E. V., Vasilyeva I. E., Busko A. E., Kunaev A. B. Estimation of Au- and Ag- particle sizes in geological samples using high time-resolved scintillation atomic emission analysis / Analit. Kontrol’. 2010. Vol. 14. N 4. P. 186 – 200 [in Russian].
Review
For citations:
Dzyuba A.A., Labusov V.A., Zarubin I.A. A new atomic-emission spectrometer Grand-2000. Industrial laboratory. Diagnostics of materials. 2022;88(1(II)):27-33. (In Russ.) https://doi.org/10.26896/1028-6861-2022-88-1-II-27-33