Сенсорный гранулированный материал на основе импрегнированного композита «сшитый поливиниловый спирт – магнетит» для определения углеводов методом оптической микрометрии

Рассмотрены получение композитного материала «сшитый поливиниловый спирт – магнетит», импрегнированного раствором тетрабората натрия, и его применение в качестве чувствительного элемента для определения углеводов в водных растворах методом оптической микрометрии. Методом ИК-спектроскопии подтверждена химическая структура исследуемого полимера. С помощью кривых намагничивания рассчитано содержание частиц Fe₃O₄ в гранулах поливинилового спирта (ПВС). Показано, что при pH среды 6,8 внедрение магнетита в гранулы сужает диапазон определяемых содержаний углеводов и снижает чувствительность матрицы ПВС к ним; однако при pH 8,6 наличие частиц Fe₃O₄ в гранулах не увеличивает предел обнаружения глюкозы и фруктозы (7,9 ммоль/дм³), но позволяет снизить относительные стандартные отклонения их определения до 3 % масс. Сенсорные гранулы с оптимальным содержанием магнетита (1,54 %) апробированы при определении методом оптической микрометрии суммарного содержания углеводов в образцах натуральных сиропов с высоким содержанием фруктозы. Полученные результаты хорошо согласуются с данными, указанными производителями сиропов.

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