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Research of the chemical composition and structure of copper nanoparticle obtained by the plasmochemical method
https://doi.org/10.26896/1028-6861-2025-91-12-56-62
Abstract
Transition metals, as trace elements, play an important role in redox reactions in the human body and act as catalysts in enzymes, and exhibit pronounced biological activity in the form of nanoparticles. The paper presents the results of a study of the chemical composition and structure of nanoparticle fractions using X-ray methods. The physicochemical parameters of copper nanoparticles obtained by plasmochemical method were analyzed. The nanoparticle sizes were determined by backscattering and scanning electron microscopy. The phase composition of nanoparticles of various dispersities and the chemical composition of their surface have been qualitatively determined and quantified. It has been established that the surface of copper nanoparticles is represented by oxide forms. The ratio of oxide forms in the total volume of coarse and fine nanoparticles was determined. The results obtained can be used in studies of the processes of modification of the surface of nanoparticles by various functional groups, and the adsorption of high-molecular-weight surfactants on the surface of nanoparticles to increase biocompatibility.
About the Authors
V. B. Borodulin
MIREA — Russian Technological University
Russian Federation
Russian Federation
Vladimir B. Borodulin
78, prosp. Vernadskogo, Moscow, 119454
E. V. Mironova
MIREA — Russian Technological University
Russian Federation
Russian Federation
Elena V. Mironova
78, prosp. Vernadskogo, Moscow, 119454
M. A. Lazov
MIREA — Russian Technological University
Russian Federation
Russian Federation
Mikhail A. Lazov
78, prosp. Vernadskogo, Moscow, 119454
Ya. V. Borodulin
Erisman Federal Scientific Center of Hygiene, Federal Service For Surveillance on Consumer Rights Protection and Human Well-Being
Russian Federation
Russian Federation
Yaroslav V. Borodulin
18, Nauchny proezd, Moscow, 117246
References
1. Borodulin V. B., Matasov A. D., Goroshinskaya I. A., et al. Physical properties studying of copper nanoparticle associates possessing biological action / Ross. Nanotekhnol. 2019. Vol. 14. Nos. 1 – 2. P. 81 – 89 [in Russian]. DOI: 10.21517/1992-7223-2019-1-2-76-84
2. Martines-Duart J., Martin-Palma R., Agullo-Rueda F. Nanotechnology for Microelectronics and Optoelectronics. — Moscow: Tekhnosfera, 2007. — 368 p. [Russian translation].
3. Shmidt V. Optical Spectroscopy in Chemistry and Life Sciences. — Moscow: Tekhnosfera, 2007. — 368 p. [in Russian].
4. Landsberg G. S. Optics. — Moscow: Nauka, 1976. — 926 p. [in Russian].
5. Maiorova T. L., Klyuev V. G., Semenov V. N., et al. Luminescent properties of polycrystalline cadmium films alloyed with metals of the first group / Vestn. VGU. 2005. No. 2. P. 38 – 44 [in Russian].
6. Menshchikova E. B., Lankin V. Z., Zenkov N. K., et al. Oxidative stress. Prooxidants and antioxidants. — Moscow: Slovo, 2006. — 556 p. [in Russian].
7. Rakitsky V. N., Yudina T. V. Antioxidant and trace element status of the body: modern diagnostic problems / Vestn. RAMN. 2005. No. 3. P. 33 – 36 [in Russian].
8. Shumaev K. B., Zabbarova I. V., Ruge E. K., Vanin A. F. The effect of reactive oxygen species and nitrogen on the release of iron ions from ferritin and the synthesis of dinitrosyl iron complexes / Biofizika. 2003. Vol. 48. No. 1. P. 5 – 9 [in Russian].
9. Serezhenkov V. A., Kalinina E. V., Glazunova V. A., et al. Why does iron eliminate the toxic effect of S-nitrosothiols on animal and human cell culture? / Biofizika. 2007. Vol. 52. No. 5. P. 869 – 875 [in Russian].
10. Kudrin A. V., Gromova O. M. Trace elements in immunology and oncology. — Moscow: GEOTAR-Media, 2007. — 544 p. [in Russian].
11. Ojo O. A., Olayide I. I., Akalabu M. C., et al. Nanoparticles and their Biomedical Applications / Biointerface Res. Appl. Chem. 2021. Vol. 11. No. 1. P. 8431 – 8445. DOI: 10.33263/briac111.84318445
12. Arsenteva I. P., Zotova E. S., Folmanis G. E., et al. Certification of metal nanoparticles used as biologically active drugs / Nanotekhnika. 2007. No. 2. P. 72 – 77 [in Russian].
13. Synthesis, Functionalization and Surface Treatment of Nanoparticles. — Los-Angeles: Am. Sci. Pub., 2002. — 350 p.
14. Nie S., Xing Y., Kim G., Simons J. Nanotechnology application in Cancer / Annu. Rev. Biomed. Eng. 2007. Vol. 9. P. 257 – 288. DOI: 10.1146/annurev.bioeng.9.060906.152025
15. Altammar K. A. A review on nanoparticles: characteristics, synthesis, applications, and challenges / Frontiers Microbiol. 2023. Vol. 14. P. 1155622. DOI: 10.3389/fmicb.2023.1155622
16. Wang N., Tian X., Song P., et al. The influence of cuprous oxide nanoparticles on photosynthetic efficiency, antioxidant responses and grain quality throughout the soybean life cycle / Agronomy. 2024. Vol. 14. P. 1821. DOI: 10.3390/agronomy14081821
17. Lakhtin V. M., Afanasev S. S., Lakhtin M. V., et al. Nanotechnologies and prospects of their use in medicine and biotechnology / Vestn. RAMN. 2008. No. 4. P. 50 – 55 [in Russian].
18. Gopinath K., Sathishkumar G., Xu L. An overview of the copper oxide nanofillers integrated in food packaging systems / Coatings. 2024. Vol. 14. P. 81. DOI: 10.3390/coatings14010081
19. Falke P. B., Shelke P. G., Hatwar P. R., et al. A comprehensive review on nanoparticle: characterization, classification, synthesis method, silver nanoparticles and its applications / GSC Biol. Pharm. Sci. 2024. Vol. 28. No. 1. P. 171 – 184. DOI: 10.30574/gscbps.2024.28.1.0268
20. Sune P. R., Jumde K. S., Hatwar P. R., et al. Nanoparticles: classification, types and applications: a comprehensive review / GSC Biol. Pharm. Sci. 2024. Vol. 29. No. 3. P. 190 – 197. DOI: 10.30574/gscbps.2024.28.1.0268
21. Goldberg E. D., Dygai A. M., Shakhov V. P. Methods of tissue culture in hematology. — Tomsk: TGU, 1992. — 272 p. [in Russian].
22. Yarilin A. A. Principles and ways of using cytokines in antitumor therapy / Allergiya Astma Klin. Immunol. 1999. No. 10. P. 3 – 16 [in Russian].
23. Rosenberg S., Lotze M., Muul L., et al. Observations on the systemic administration of autologous lymphokine-activated killer cells and recombinant IL-2 to patients with metastatic cancer / New Engl. J. Med. 1985. No. 313. P. 1485 – 1492. DOI: 10.1056/nejm198512053132327
24. Berezhnaya N. M., Chekhun V. F. Immunology of malignant growth. — Kiev: Naukova dumka, 2005. — 790 p. [in Russian].
25. Rehr J. J., Kas J. J., Vila F. D., et al. Parameter-free calculations of X-ray spectra with FEFF9 / Phys. Chem. Chem. Phys. 2010. Vol. 12. P. 5503 – 5513. DOI: 10.1039/b926434e
26. Martynov L. Yu., Sitnikova T. V., Lazov M. A., et al. Using an activated copper microelectrode for voltammetric determination of alcohols / Tonkie Khim. Tekhnol. 2018. Vol. 13. No. 1. P. 22 – 32 [in Russian]. DOI: 10.32362/2410-6593-2018-13-1-22-32
Review
For citations:
Borodulin V.B., Mironova E.V., Lazov M.A., Borodulin Ya.V. Research of the chemical composition and structure of copper nanoparticle obtained by the plasmochemical method. Industrial laboratory. Diagnostics of materials. 2025;91(12):56-62. (In Russ.) https://doi.org/10.26896/1028-6861-2025-91-12-56-62
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