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THE ANALYSIS OF ELECTROPHYSICAL PROPERTIES OF VEGETABLE OILS BY THERMALLY ACTIVATED CURRENT SPECTROSCOPY

https://doi.org/10.26896/1028-6861-2018-84-2-38-42

Abstract

A promising way for quality diagnosis of socially significant food products is using of the methods based on phenomenon of electrical polarization and/or electromagnetism in a liquid dielectric medium. In this paper, the interrelation between quality features and electrophysical properties of olive oil has been experimentally proved, and a method of thermally activation current spectroscopy has been propose to evaluate the fatty acid composition and degree of oxidative damage. The main oil components — triglycerides of fatty acids and their little stable associates — contain polar functional groups and unsaturated chemical bonds, which are capable for ionizing, polarizing and electric charge transferring. It is shown that thermally conditioned associates disintegration gives an electrophysical response, registered as thermally stimulated current, and the same type of associates disintegrated in certain temperature ranges. The presence or absence of characteristic current peaks can be a diagnostic feature describing the fatty acid composition and oil quality. Thus, thermally activation current spectroscopy is an informative method for analyzing food fats, and its application makes it possible to obtain an integral electrophysical characteristic — the distribution of current peaks on a temperature scale. By the type of spectrum, it is possible to determine oil species or to fix some indistinctive diagnostic features.

About the Author

Zh. V. Kadolich
Belarusian Trade and Economics University of Consumer Cooperatives
Belarus

Zhanna V. Kadolich

Gomel


References

1. Ukhartseva I. Yu., Tsvetkova E. A. Methods and means of research: a course of lectures. — Gomel’: Belorusskii torgovo-ékonomicheskii universitet potrebitel’skoi kooperatsii, 2013. — 212 p. [in Russian].

2. Ukhartseva I. Yu., Kadolich Zh. V., Tkacheva L. V. Research methods of alimentary raw materials and foodstuffs, and their experience / Potreb. Koop. 2014. N 1(44). P. 66 – 74 [in Russian].

3. Krishtafovich V. I., Krishtafovich D. V., Eremeeva N. V. Physicochemical methods of research: a textbook for bachelors. — Moscow: Dashkov i Ko, 2015. — 208 p. [in Russian].

4. Kadolich Zh. V., Delikatnaya I. O., Tsvetkova E. A. Vegetable oils: the consumer market, adulteration, quality control methods / Potreb. Koop. 2012. N 4(39). P. 82 – 91 [in Russian].

5. Lisitsyn A. N., Grigor’eva V. N. Scientific principles of obtaining environmentally safe fat and oil products / Khran. Pererab. Sel’khozsyr’ya. 2008. N 12. P. 40 – 42 [in Russian].

6. Ukhartseva I. Yu., Tsvetkova E. A., Kadolich Zh. V. Application of the isothermal depolarization method in food industry / Potreb. Koop. 2016. N 2(53). P. 77 – 81 [in Russian].

7. Igolkin B. I. et al. Electrical conductivity of vegetable oils as a function of temperature and frequency of electromagnetic oscillations / Nauchn.-Tekhn. Vedom. SPbGPU. 2011. N 2. P. 278 – 282 [in Russian].

8. RF Pat. 2517763, MPK G 01 N 27/06. Method for controlling the degree of purification by the stages of refining vegetable oils / Volovei A. G. et al.; applicant and owner SPbGTÉU. — N 2012132677/28; appl. 30.07.12; publ. 27.05.14. On-line: http://www.fips.ru.

9. RF Pat. 2507511, MPK G 01 N 27/06. Method for quality control (safety) of vegetable oils and melted fats / Volovei A. G. et al.; applicant and owner SPbGTÉU. — N 2012132676/28; appl. 30.07.2012; publ. 20.02.2014. On-line: http://www.fips.ru.

10. RF State Standard GOST 25209–82. Plastics and polymer films. Methods of determination of surface charges of electrets. — Moscow: Goskomitet SSSR po standartam, 1982. — 12 p. [in Russian].

11. Kestelman N., Pinchuk L., Goldade V. Electrets in Engineering: Fundamentals and Applications. — Boston: Kluver Academic Publishers, 2000. — 281 p.

12. Gol’dade V. A. et al. Study of polymer crazing using thermoactivation current spectroscopy / Zavod. Lab. Diagn. Mater. 2016. N 10(82). P. 33 – 36 [in Russian].

13. Kadolich Zh. V. et al. Estimation of properties of vegetable oils by the method of thermoactivation current spectroscopy / Maslozhir. Promyshl. 2013. N 2. P. 20 – 22 [in Russian].

14. Kadolich Zh. V. et al. Rapeseed oil: importance in the Belarusian market, basic properties and perspective method of research / Vestn. Mogilev. Gos. Univ. Prodovol’st. 2015. N 1(18). P. 50 – 55 [in Russian].

15. Kadolich Zh. V. et al. Experimental justification of identity feature choice of palm oils / Prib. Metody Izmer. 2015. N 1(10). P. 99 – 103 [in Russian].

16. Eliseeva L. G. et al. Commodity studies of homogeneous groups of food products: a textbook for bachelors. — Moscow: Dashkov i Ko, 2014. — 930 p. [in Russian].


Review

For citations:


Kadolich Zh.V. THE ANALYSIS OF ELECTROPHYSICAL PROPERTIES OF VEGETABLE OILS BY THERMALLY ACTIVATED CURRENT SPECTROSCOPY. Industrial laboratory. Diagnostics of materials. 2018;84(2):38-42. (In Russ.) https://doi.org/10.26896/1028-6861-2018-84-2-38-42

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ISSN 1028-6861 (Print)
ISSN 2588-0187 (Online)